The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
RAFT Polymerization of Pentafluorophenyl Methacrylate: Preparation of Reactive Linear Diblock Copolymers
Abstract
Summary: Reversible addition fragmentation chain transfer (RAFT) polymerization of pentafluorophenyl methacrylate (PFMA) was carried out in the presence of cumyldithiobenzoate and 4‐cyano‐4‐((thiobenzoyl)sulfanyl)pentanoic acid, respectively. These chain transfer agents with 2,2′‐azoisobutyronitrile (AIBN) as initiator yielded the active ester polymer poly(PFMA) with $\overline M _{\rm n}$ up to 17 000 g · mol−1 and low polydispersity index ($\overline M _{\rm w} /\overline M _{\rm n}$ < 1.2). Kinetic analysis using 19 F NMR spectroscopy and gel permeation chromatography (GPC) measurements showed controlled polymerization behavior for both chain transfer agents. Successful preparation of linear diblock copolymers consisting of an active ester block and methyl methacrylate, N‐acryloylmorpholine, or N,N‐diethylacrylamide, respectively, could be demonstrated. These polymers could easily react with amines in a polymer analogous reaction to form multifunctional polymers. magnified image
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Cites
Chong, ). Y. K., Le, T. P. T., Moad, G., Rizzardo, E., & Thang, S. H. (1999) · Macromolecules · doi:10.1021/ma981472p · Cited by 850
Controlled/living radical polymerization in aqueous media: homogeneous and heterogeneous systems
Qiu, J., Charleux, B., & Matyjaszewski, K. (2001) · Progress in Polymer Science · doi:10.1016/s0079-6700(01)00033-8 · Cited by 595
Cited by
Radical addition–fragmentation chemistry in polymer synthesis
Moad, G., Rizzardo, E., & Thang, S. H. (2008) · Polymer · doi:10.1016/j.polymer.2007.11.020 · Cited by 1,397
Bioapplications of RAFT Polymerization
Boyer, C., Bulmus, V., Davis, T. P., Ladmiral, V., Liu, J., & Perrier, S. (2009) · Chemical Reviews · doi:10.1021/cr9001403 · Cited by 1,015
Living Radical Polymerization by the RAFT Process—A First Update
Moad, G., Rizzardo, E., & Thang, S. H. (2006) · Australian Journal of Chemistry · doi:10.1071/ch06250 · Cited by 848
50th Anniversary Perspective: Polymer Functionalization
Blasco, E., Sims, M. B., Goldmann, A. S., Sumerlin, B. S., & Barner-Kowollik, C. (2017) · Macromolecules · doi:10.1021/acs.macromol.7b00465 · Cited by 437
Liquid Crystalline Ordering and Charge Transport in Semiconducting Materials
Pisula, W., Zorn, M., Chang, J. Y., Müllen, K., & Zentel, R. (2009) · Macromolecular Rapid Communications · doi:10.1002/marc.200900251 · Cited by 400
Metadata
- Authors
- Eberhardt, M., & Théato, P.
- Venue
- Macromolecular Rapid Communications
- Publisher
- Wiley
- Published
- 2005-09-08
- Volume
- 26
- Issue
- 18
- Pages
- 1488-1493
- ISSN
- 1022-1336 (ISSN-L)
- 1521-3927
- OpenAlex
- W2010098607
- Cited by
- 209
- References
- 2
- FWCI
- 5.95
- Type
- journal article
- Language
- en
- Open access
- closed
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- Eberhardt, M., & Théato, P. (2005). RAFT Polymerization of Pentafluorophenyl Methacrylate: Preparation of Reactive Linear Diblock Copolymers. Macromolecular Rapid Communications. https://doi.org/10.1002/marc.200500390
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