The DOI matches its Crossref record; 314 of the 314 references it cites were found in a registry or an index.
Experimental Requirements for an Efficient Control of Free‐Radical Polymerizations via the Reversible Addition‐Fragmentation Chain Transfer (RAFT) Process
Abstract
Summary: Reversible addition‐fragmentation chain transfer (RAFT) polymerization is a recent and very versatile controlled radical polymerization technique that has enabled the synthesis of a wide range of macromolecules with well‐defined structures, compositions, and functionalities. The RAFT process is based on a reversible addition‐fragmentation reaction mediated by thiocarbonylthio compounds used as chain transfer agents (CTAs). A great variety of CTAs have been designed and synthesized so far with different kinds of substituents. In this review, all of the CTAs encountered in the literature from 1998 to date are reported and classified according to several criteria : i) the structure of their substituents, ii) the various monomers that they have been polymerized with, and iii) the type of polymerization that has been performed (solution, dispersed media, surface initiated, and copolymerization). Moreover, the influence of various parameters is discussed, especially the CTA structure relative to the monomer and the experimental conditions (temperature, pressure, initiation, CTA/initiator ratio, concentration), in order to optimise the kinetics and the efficiency of the molecular‐weight‐distribution control. Schematic of the RAFT polymerization. magnified imageSchematic of the RAFT polymerization.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Atom Transfer Radical Polymerization
Matyjaszewski, K., & Xia, J. (2001) · Chemical Reviews · doi:10.1021/cr940534g · Cited by 7,654
Chiefari, J., Chong, Y. K. (., Ercole, F., Krstina, J., Jeffery, J., Le, T. P. T., Mayadunne, R. T. A., Meijs, G. F., Moad, C. L., Moad, G., et al. (1998) · Macromolecules · doi:10.1021/ma9804951 · Cited by 5,147
New Polymer Synthesis by Nitroxide Mediated Living Radical Polymerizations
Hawker, C. J., Bosman, A. W., & Harth, E. (2001) · Chemical Reviews · doi:10.1021/cr990119u · Cited by 3,850
Metal-Catalyzed Living Radical Polymerization
Kamigaito, M., Ando, T., & Sawamoto, M. (2001) · Chemical Reviews · doi:10.1021/cr9901182 · Cited by 3,275
Living Radical Polymerization by the RAFT Process
Moad, G., Rizzardo, E., & Thang, S. H. (2005) · Australian Journal of Chemistry · doi:10.1071/ch05072 · Cited by 2,288
Peppas, N. A. (1992) · Journal of Controlled Release · doi:10.1016/0168-3659(92)90108-4 · Cited by 2,043
A new method for the deoxygenation of secondary alcohols
Barton, D. H. R., & McCombie, S. W. (1975) · Journal of the Chemical Society, Perkin Transactions 1 · doi:10.1039/p19750001574 · Cited by 1,652
SZWARC, M. (1956) · Nature · doi:10.1038/1781168a0 · Cited by 1,360
Fischer, H. (2001) · Chemical Reviews · doi:10.1021/cr990124y · Cited by 1,344
Perrier, S., & Takolpuckdee, P. (2005) · Journal of Polymer Science Part A: Polymer Chemistry · doi:10.1002/pola.20986 · Cited by 1,130
Cited by
Controlled/living radical polymerization: Features, developments, and perspectives
Braunecker, W. A., & Matyjaszewski, K. (2007) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2006.11.002 · Cited by 3,202
Radical addition–fragmentation chemistry in polymer synthesis
Moad, G., Rizzardo, E., & Thang, S. H. (2008) · Polymer · doi:10.1016/j.polymer.2007.11.020 · Cited by 1,397
Gregory, A., & Stenzel, M. H. (2012) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2011.08.004 · Cited by 470
YORK, A., KIRKLAND, S., & MCCORMICK, C. (2008) · Advanced Drug Delivery Reviews · doi:10.1016/j.addr.2008.02.006 · Cited by 349
Barner, L., Davis, T. P., Stenzel, M. H., & Barner‐Kowollik, C. (2007) · Macromolecular Rapid Communications · doi:10.1002/marc.200600805 · Cited by 339
Metadata
- Authors
- Favier, A., & Charreyre, M.
- Venue
- Macromolecular Rapid Communications
- Publisher
- Wiley
- Published
- 2006-04-27
- Volume
- 27
- Issue
- 9
- Pages
- 653-692
- ISSN
- 1022-1336 (ISSN-L)
- 1521-3927
- OpenAlex
- W1966090112
- Cited by
- 461
- References
- 314
- FWCI
- 36.09
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Experimental Requirements for an Efficient Control of Free‐Radical Polymerizations via the Reversible Addition‐Fragmentation Chain Transfer (RAFT) Process. https://app.cochat.ai/papers/10.1002/marc.200500839
- The paper
- Favier, A., & Charreyre, M. (2006). Experimental Requirements for an Efficient Control of Free‐Radical Polymerizations via the Reversible Addition‐Fragmentation Chain Transfer (RAFT) Process. Macromolecular Rapid Communications. https://doi.org/10.1002/marc.200500839
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
