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Functionalized Graphenes and Thermoplastic Nanocomposites Based upon Expanded Graphite Oxide
Open accessAbstract
Exfoliation of expanded GO represents an attractive route to functionalized graphenes as versatile 2D carbon nanomaterials and components of a wide variety of polymer nanocomposites. Thermally reduced graphite oxides (TrGO) with specific surface areas of 600 to 950 m 2 · g−1 were obtained by oxidation of graphite followed by thermal expansion at 600 °C. Thermal post treatment at 700 °C and 1 000 °C increased carbon content (81 to 97 wt.‐%) and lowered resistivity (1 600 to 50 Ω · cm). During melt extrusion with PC, iPP, SAN and PA6, exfoliation afforded uniformly dispersed graphenes with aspect ratio > 200. In comparison to conventional 0D and 1D carbon nanoparticles, TrGO afforded nanocomposites with improved stiffness and lower percolation threshold. Recent progress and new strategies in development of functionalized graphenes and graphene‐based nanocomposites are highlighted. magnified image
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Adsorption of Gases in Multimolecular Layers
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Graphene-based composite materials
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Two-dimensional atomic crystals
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Graphene/Polymer Nanocomposites
Kim, H., Abdala, A. A., & Macosko, C. W. (2010) · Macromolecules · doi:10.1021/ma100572e · Cited by 3,406
Covalent polymer functionalization of graphene nanosheets and mechanical properties of composites
Fang, M., Wang, K., Lu, H., Yang, Y., & Nutt, S. (2009) · Journal of Materials Chemistry · doi:10.1039/b908220d · Cited by 1,309
Graphene-polymer nanocomposites for structural and functional applications
Hu, K., Kulkarni, D. D., Choi, I., & Tsukruk, V. V. (2014) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2014.03.001 · Cited by 1,085
Polymer Nanocomposites—A Comparison between Carbon Nanotubes, Graphene, and Clay as Nanofillers
Bhattacharya, M. (2016) · Materials · doi:10.3390/ma9040262 · Cited by 747
Size selection of dispersed, exfoliated graphene flakes by controlled centrifugation
Khan, U., O’Neill, A., Porwal, H., May, P., Nawaz, K., & Coleman, J. N. (2012) · Carbon · doi:10.1016/j.carbon.2011.09.001 · Cited by 309
Metadata
- Authors
- Steurer, P., Wissert, R., Thomann, R., & Mülhaupt, R.
- Venue
- Macromolecular Rapid Communications
- Publisher
- Wiley
- Published
- 2009-02-06
- Volume
- 30
- Issue
- 4-5
- Pages
- 316-327
- ISSN
- 1022-1336 (ISSN-L)
- 1521-3927
- OpenAlex
- W2085375096
- Cited by
- 522
- References
- 4
- FWCI
- 28.15
- Type
- journal article
- Language
- en
- Open access
- bronze
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