Discrete Metal Catalysts for Stereoselective Ring‐Opening Polymerization of Chiral Racemic β‐Lactones
Abstract
Poly(β‐hydroxyalkanoate)s (PHAs) are a class of aliphatic polyesters that can be efficiently synthesized by ring‐opening polymerization (ROP) of β‐lactones. The case of chiral racemic β‐substituted β‐lactones is particularly appealing since these monomers open the way to original tacticities and materials different from those biotechnologically produced. In this overview, after briefly surveying general considerations associated to the ROP of β‐lactones and metal‐based catalysts used in stereoselective ROP of racemic β‐butyrolactone, special emphasis is given to discrete rare earth catalysts that have allowed the preparation of highly syndiotactic poly(3‐hydroxybutyrate)s. Recent developments – such as preparation of stereocontrolled PHAs with pendant structural groups via (co)polymerization of functional β‐substituted β‐lactones, and highly alternating copolymers obtained by ROP of mixtures of enantiomerically pure but different monomers – are also discussed. magnified image
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Syndiotactic PHAs have been synthesized by stereospecific ROP of racemic β-lactones by several rare-earth metal catalysts.
“Syndiotactic poly(3-hydroxyalkanoate)s (PHAs) have been synthesized by stereospecific ROP of racemic b-lactones by several rare-earth metal catalysts.318”
From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [318]
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- Authors
- Carpentier, J.
- Affiliations
- Centre National de la Recherche Scientifique (FR)
- Corresponding author
- Carpentier, Jean‐François
- Venue
- Macromolecular Rapid Communications
- Publisher
- Wiley
- Published
- 2010-06-22
- Volume
- 31
- Issue
- 19
- Pages
- 1696-1705
- ISSN
- 1022-1336 (ISSN-L)
- 1521-3927
- OpenAlex
- W2066741641
- Cited by
- 192
- References
- 62
- Citations by year
- 2026: 5 · 2025: 7 · 2024: 6 · 2023: 10 · 2022: 16 · 2021: 6 · 2020: 12 · 2019: 8 · 2018: 16 · 2017: 18 · 2016: 15 · 2015: 13 · 2014: 14 · 2013: 18 · 2012: 11
- FWCI
- 5.94
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Macromolecular Rapid Communications (publishedVersion)
- PubMed (publishedVersion)
- HAL (submittedVersion)
- Funders
- Agence Nationale de la Recherche (ANR-06-BLAN-0213)
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Chemistry › Organic Chemistry › Asymmetric Synthesis and Catalysis
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Keywords
- polyhydroxyalkanoates, ring-opening polymerization, β-lactones, stereoselective polymerization, rare earth catalysts, tacticity control, pendant functional groups, copolymerization, alternating copolymers
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