Amphiphilic block copolymers from a direct and one-pot raft synthesis in water
Abstract
The syntheses of amphiphilic block copolymers are successfully performed in water by chain extension of hydrophilic macromolecules with styrene at 80 °C. The employed strategy is a one-pot procedure in which poly(acrylic acid), poly(methacrylic acid) or poly(methacrylic acid-co-poly(ethylene oxide) methyl ether methacrylate) macroRAFTs are first formed in water using 4-cyano-4-thiothiopropylsulfanyl pentanoic acid (CTPPA) as a chain transfer agent. The resulting macroRAFTs are then directly used without further purification for the RAFT polymerization of styrene in water in the same reactor. This simple and straightforward strategy leads to a very good control of the resulting amphiphilic block copolymers.
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Chaduc et al. reported a simple one-pot RAFT process for amphiphilic block copolymers in water.
“In contrast to this two-step process, Chaduc et al. reported a simple one-pot RAFT process for amphiphilic block copolymers in water [33].”
From Block Copolymers: Synthesis, Self-Assembly, and Applications (2017) · cites this paper as [33]
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Block Copolymers: Synthesis, Self-Assembly, and Applications
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“In contrast to this two-step process, Chaduc et al. reported a simple one-pot RAFT process for amphiphilic block copolymers in water [ 33].”
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- Authors
- Chaduc, I., Zhang, W., Rieger, J., Lansalot, M., D'Agosto, F., & Charleux, B.
- Affiliations
- Lyon 1 Université (FR)
- Centre National de la Recherche Scientifique (FR)
- Corresponding author
- Lansalot, Muriel
- Venue
- Macromolecular Rapid Communications
- Publisher
- Wiley
- Published
- 2011-06-30
- Volume
- 32
- Issue
- 16
- Pages
- 1270-1276
- ISSN
- 1022-1336 (ISSN-L)
- 1521-3927
- OpenAlex
- W2128291348
- Cited by
- 138
- References
- 27
- Citations by year
- 2025: 3 · 2024: 4 · 2023: 7 · 2022: 10 · 2021: 11 · 2020: 13 · 2019: 7 · 2018: 9 · 2017: 11 · 2016: 17 · 2015: 10 · 2014: 12 · 2013: 10 · 2012: 10
- FWCI
- 5.41
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Macromolecular Rapid Communications (publishedVersion)
- PubMed (publishedVersion)
- HAL (submittedVersion)
- Topics
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Physical Sciences › Materials Science › Materials Chemistry › Block Copolymer Self-Assembly
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Keywords
- amphiphilic block copolymers, RAFT polymerization, one-pot synthesis, chain extension, styrene, poly(acrylic acid), poly(methacrylic acid), chain transfer agent, aqueous polymerization, block copolymer synthesis
- MeSH terms
- Acrylates, Methacrylates, Polymers, Styrene, Hydrophobic and Hydrophilic Interactions, Polymerization
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