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Self‐healing in Nanocomposite Hydrogels
Abstract
Polymer hydrogels with characteristics distinct from those of solid materials are one of the most promising candidates for smart materials. Here, we report that a nanocomposite hydrogel (NC gel) consisting of a unique polymer/clay network structure, can exhibit complete self‐healing through autonomic reconstruction of crosslinks across a damaged interface. Mechanical damage in NC gels can be repaired without the use of a healing agent, and even sections of NC gels separated by cutting, from whichever the same or different kinds of NC gel, perfectly (re‐)combine by just contacting the cut surfaces together at mildly elevated temperatures. In NC gels, the autonomic fusion of cut surfaces as well as the self‐healing could be achieved not only immediately after being cut but also after a long waiting time. magnified image
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Citations
Cited by
Fracture and adhesion of soft materials: a review
Creton, C., & Ciccotti, M. (2016) · Reports on Progress in Physics · doi:10.1088/0034-4885/79/4/046601 · Cited by 915
Self-healing gels based on constitutional dynamic chemistry and their potential applications
Wei, Z., Yang, J. H., Zhou, J., Xu, F., Zrínyi, M., Dussault, P. H., Osada, Y., & Chen, Y. M. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00219a · Cited by 896
“Nonswellable” Hydrogel Without Mechanical Hysteresis
Kamata, H., Akagi, Y., Kayasuga-Kariya, Y., Chung, U.-I., & Sakai, T. (2014) · Science · doi:10.1126/science.1247811 · Cited by 669
Poly(vinyl alcohol) Hydrogel Can Autonomously Self-Heal
Zhang, H., Xia, H., & Zhao, Y. (2012) · ACS Macro Letters · doi:10.1021/mz300451r · Cited by 509
Deng, Z., Hu, T., Lei, Q., He, J., Ma, P. X., & Guo, B. (2019) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.8b20178 · Cited by 486
Metadata
- Authors
- Haraguchi, K., Uyama, K., & Tanimoto, H.
- Venue
- Macromolecular Rapid Communications
- Publisher
- Wiley
- Published
- 2011-07-05
- Volume
- 32
- Issue
- 16
- Pages
- 1253-1258
- ISSN
- 1022-1336 (ISSN-L)
- 1521-3927
- OpenAlex
- W2021055214
- Cited by
- 321
- References
- 0
- FWCI
- 17.18
- Type
- journal article
- Language
- en
- Open access
- closed
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