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Visible‐Light‐Mediated Thiol‐Ene Hydrogelation Using Eosin‐Y as the Only Photoinitiator
Abstract
The utility of visible‐light‐mediated polymerization in tissue engineering has been limited due to the necessary use of potentially cytotoxic coinitiator and comonomer. Here, we report a visible‐light‐mediated thiol‐ene hydrogelation scheme using eosin‐Y as the only photoinitiator. Under visible light exposure, rapid and highly tunable step‐growth gelation is achieved using PEG‐norbornene and a model cross‐linker dithiothreitol. In addition to investigating the gelation kinetics and properties of thiol‐ene hydrogels formed by this new gelation scheme, we also report high cytocompatibility of these hydrogels using human mesenchymal stem cells (hMSCs) and pancreatic MIN6 β‐cells.
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Photopolymerizable hydrogels for tissue engineering applications
Nguyen, K. T., & West, J. L. (2002) · Biomaterials · doi:10.1016/s0142-9612(02)00175-8 · Cited by 1,669
Photoreversible Patterning of Biomolecules within Click‐Based Hydrogels
DeForest, C. A., & Anseth, K. S. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201106463 · Cited by 315
Cited by
Recent Advances in Photo-Crosslinkable Hydrogels for Biomedical Applications
Choi, J. R., Yong, K. W., Choi, J. Y., & Cowie, A. C. (2019) · BioTechniques · doi:10.2144/btn-2018-0083 · Cited by 403
An overview of injectable polymeric hydrogels for tissue engineering
Sivashanmugam, A., Arun Kumar, R., Vishnu Priya, M., Nair, S. V., & Jayakumar, R. (2015) · European Polymer Journal · doi:10.1016/j.eurpolymj.2015.05.014 · Cited by 366
3D printing of functional microrobots
Li, J., & Pumera, M. (2021) · Chemical Society Reviews · doi:10.1039/d0cs01062f · Cited by 303
Photocrosslinkable silk-based biomaterials for regenerative medicine and healthcare applications
Dey, S., Jaiswal, C., Shome, S., Bhar, B., Bandyopadhyay, A., Manikumar, K., Dadheech, R., & Mandal, B. B. (2023) · Regenerative Engineering and Translational Medicine · doi:10.1007/s40883-022-00277-8 · Cited by 24
Metadata
- Authors
- Shih, H., & Lin, C.
- Venue
- Macromolecular Rapid Communications
- Publisher
- Wiley
- Published
- 2013-02-05
- Volume
- 34
- Issue
- 3
- Pages
- 269-273
- ISSN
- 1022-1336 (ISSN-L)
- 1521-3927
- OpenAlex
- W2094761102
- Cited by
- 209
- References
- 2
- FWCI
- 8.13
- Type
- journal article
- Language
- en
- Open access
- closed
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- Shih, H., & Lin, C. (2013). Visible‐Light‐Mediated Thiol‐Ene Hydrogelation Using Eosin‐Y as the Only Photoinitiator. Macromolecular Rapid Communications. https://doi.org/10.1002/marc.201200605
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
