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Cited by 287

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Covalent Triazine‐Based Frameworks as Visible Light Photocatalysts for the Splitting of Water

Bi, Jinhong, Fang, Wei, Li, Liuyi, Wang, Jinyun, Liang, Shijing, He, Yunhui, Liu, Minghua, Wu, Ling·2015·Macromolecular Rapid Communications

Abstract

Covalent triazine‐based frameworks (CTFs) with a graphene‐like layered morphology have been controllably synthesized by the trifluoromethanesulfonic acid‐catalyzed nitrile trimerization reactions at room temperature via selecting different monomers. Platinum nanoparticles are well dispersed in CTF‐T1, which is ascribed to the synergistic effects of the coordination of triazine moieties and the nanoscale confinement effect of CTFs. CTF‐T1 exhibits excellent photocatalytic activity and stability for H 2 evolution in the presence of platinum under visible light irradiation (λ ≥ 420 nm). The activity and stability of CTF‐T1 are comparable to those of g‐C 3 N 4. Importantly, as a result of the tailorable electronic and spatial structures of CTFs that can be achieved through the judicial selection of monomers, CTFs not only show great potential as organic semiconductor for photocatalysis but also may provide a molecular‐level understanding of the inherent heterogeneous photocatalysis. image

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Metadata

Authors
Bi, J., Fang, W., Li, L., Wang, J., Liang, S., He, Y., Liu, M., & Wu, L.
Venue
Macromolecular Rapid Communications
Publisher
Wiley
Published
2015-08-21
Volume
36
Issue
20
Pages
1799-1805
ISSN
  • 1022-1336 (ISSN-L)
  • 1521-3927
OpenAlex
W2143415304
Cited by
287
References
1
FWCI
8.39
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Covalent Triazine‐Based Frameworks as Visible Light Photocatalysts for the Splitting of Water. https://app.cochat.ai/papers/10.1002/marc.201500270
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Bi, J., Fang, W., Li, L., Wang, J., Liang, S., He, Y., Liu, M., & Wu, L. (2015). Covalent Triazine‐Based Frameworks as Visible Light Photocatalysts for the Splitting of Water. Macromolecular Rapid Communications. https://doi.org/10.1002/marc.201500270

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