Ethene‐butadiene copolymers by single‐site catalysts
Open accessAbstract
Constrained geometry catalysts ([Me 2 Si(N t Bu)(Me 4 Cp)]TiCl 2) were used to copolymerize ethene and 1,3‐butadiene. It is possible to incorporate 17 mol% of butadiene, other catalyst systems such as CpTiCl 3/MAO show much lower incorporation. More than 300 000 kg of copolymer can be obtained by one mol of the catalysts in one hour. The microstructure of the copolymers has been investigated by 1 H‐ and 13 C‐NMR spectroscopy. The butadiene is incorporated mainly in 1,4‐trans‐ and 1,2‐structure. The high amount of 9‐29% of vinyl groups offers the possibility of an easy vulcanisation. The molecular weights of these elastomers are high with values of 250 000. Important is the low glass transition temperature of −28 °C of a copolymer with 7 mol% of butadiene.
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Cites
The publisher hasn’t deposited this paper’s reference list.
Research works printed but not linked: 7
- [1]W. Kaminsky, Olefin Polymerization Catalyzed by Metallocenes, Advances in Catalysis, Vol. 46, 2001, p. 89-159
- [3]R. Blom, A. Follestad, E. Rytter, M. Tilsel, M. Ystenes (eds.) Organometallic Catalyst and Olefin Polymerization, Springer (2001) Berlin
- [2]J. Scheirs, W. Kaminsky (eds.) Metallocene-Based Polyolefins Vol. I + II, Wiley (2000), Chichester
- [4]S.D. Ittel, L.K. Johnson, M. Brookhart, Chem. Rev. 2000, 100, 1169
- [6]G. Ricci, s. Italia, A. Giarusso, L. Porri, J. Organomet. Chem. 1993, 451, 67
- [7]W. Kaminsky, A. Laban, Applied Catalysis AL General 2001, 222, 47
- [6]M. Schlobohm, Dissertation, University Hamburg 1985
Cited by
Sorted by citations
Constrained geometry complexes—Synthesis and applications
Braunschweig, H., & Breitling, F. M. (2006) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2005.10.022 · Cited by 306 · see citing works
Synthesis and Deconstruction of Polyethylene-type Materials
Schwab, S. T., Baur, M., Nelson, T. F., & Mecking, S. (2024) · Chemical Reviews · doi:10.1021/acs.chemrev.3c00587 · Cited by 203 · see citing works
Takeuchi, D. (2009) · Dalton Transactions · doi:10.1039/b911992b · Cited by 178 · see citing works
Copolymerization of ethylene with cycloolefins or cyclodiolefins by a constrained‐geometry catalyst
Naga, N. (2005) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.20575 · Cited by 60 · see citing works
Installing a Trigger to Upcycle High-Density Polyethylene
Nan, T., Chen, Q., Zheng, Z., Liang, Y., Qin, Y., Wang, Y., Liu, B., & Cui, D. (2024) · Journal of the American Chemical Society · doi:10.1021/jacs.4c08958 · Cited by 42 · see citing works
Ren, X., Guo, F., Fu, H., Song, Y. Z., Li, Y., & Hou, Z. (2018) · Polymer Chemistry · doi:10.1039/c8py00039e · Cited by 43 · see citing works
Perrin, L., Bonnet, F., Chenal, T., Visseaux, M., & Maron, L. (2010) · Chemistry - A European Journal · doi:10.1002/chem.200903455 · Cited by 36 · see citing works
Olefin Polymerizations with Group IV Metal Catalysts
Resconi, L., Chadwick, J. C., & Cavallo, L. (2007) · Elsevier eBooks · doi:10.1016/b0-08-045047-4/00065-0 · Cited by 35 · see citing works
Catalytic 1,3‐Cyclohexadiene Homopolymerization and Regioselective Copolymerization with Ethylene
Heiser, D. E., Okuda, J., Gambarotta, S., et al. (2005) · Macromolecular Chemistry and Physics · doi:10.1002/macp.200400384 · Cited by 23 · see citing works
Tan, R., Shi, Z., Guo, F., He, L., Han, L., & Li, Y. (2017) · Polymer Chemistry · doi:10.1039/c7py00847c · Cited by 20 · see citing works
Ethene-1,3-butadiene copolymerizations in the presence of CpTiCl3–MAO: Relevance of the cocatalyst
Pellegrino, M., Costabile, C., Grisi, F., & Pragliola, S. (2008) · European Polymer Journal · doi:10.1016/j.eurpolymj.2008.05.027 · Cited by 15 · see citing works
Sun, B., & Liu, B. (2024) · Macromolecules · doi:10.1021/acs.macromol.4c00580 · Cited by 14 · see citing works
Copolymerization of Ethylene with Conjugated Dienes
Belaid, I., Monteil, V., & Boisson, C. (2018) · Wiley eBooks · doi:10.1002/9781119242277.ch18 · Cited by 8 · see citing works
- Authors
- Kaminsky, W., & Hinrichs, B.
- Affiliations
- Universität Hamburg (DE)
- ORCID
- Kaminsky, Walter
- Venue
- Macromolecular Symposia
- Publisher
- Wiley
- Published
- 2003-07
- Volume
- 195
- Issue
- 1
- Pages
- 39-44
- ISSN
- 1022-1360 (ISSN-L)
- 1521-3900
- OpenAlex
- W2047618966
- Cited by
- 14
- References
- 0
- Citations by year
- 2024: 3 · 2018: 2 · 2017: 1
- FWCI
- 0.94
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Locations
- Macromolecular Symposia (publishedVersion)
- Topics
- Physical Sciences › Chemistry › Organic Chemistry › Organometallic Complex Synthesis and Catalysis
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Keywords
- constrained geometry catalysts, single-site catalysts, copolymer microstructure, vinyl groups, vulcanization, glass transition temperature, metallocene catalysis
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
