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The effect of molecular weight on the crystallization kinetics of polycaprolactone
Abstract
The crystallization kinetics and degree of crystallinity of polycaprolactone (PCL) were studied using the technique of differential scanning calorimetry (DSC). The crystallization exotherms measured using DSC were analyzed using a modified Avrami equation. The modification limited the analysis of the data to the primary crystallization process, where the Avrami equation is applicable. Both the degree of crystallinity and primary composite rate constant were found to decrease with increasing molecular weight. The observations have been explained in terms of the unified reptation‐nucleation theory. Copyright © 2006 John Wiley & Sons, Ltd.
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Cites
Biodegradation and biocompatibility of PLA and PLGA microspheres
Anderson, J. M., & Shive, M. S. (1997) · Advanced Drug Delivery Reviews · doi:10.1016/s0169-409x(97)00048-3 · Cited by 2,617
Biodegradable blends and composites of polycaprolactone and starch derivatives
Koenig, M. F., & Huang, S. J. (1995) · Polymer · doi:10.1016/0032-3861(95)90934-t · Cited by 336
Cited by
Poly-є-caprolactone based formulations for drug delivery and tissue engineering: A review
Dash, T. K., & Konkimalla, V. B. (2012) · Journal of Controlled Release · doi:10.1016/j.jconrel.2011.09.064 · Cited by 1,016
Effect of Molecular Weight on the Crystallization and Melt Memory of Poly(ε-caprolactone) (PCL)
Fernández-Tena, A., Pérez-Camargo, R. A., Coulembier, O., Sangroniz, L., Aranburu, N., Guerrica-Echevarria, G., Liu, G., Wang, D., Cavallo, D., & Müller, A. J. (2023) · Macromolecules · doi:10.1021/acs.macromol.3c00234 · Cited by 200
Hou, Y., Wang, W., & Bartolo, P. (2022) · Materials & Design · doi:10.1016/j.matdes.2022.110582 · Cited by 75
Navarro-Baena, I., Kenny, J. M., & Peponi, L. (2014) · Polymer Degradation and Stability · doi:10.1016/j.polymdegradstab.2014.03.012 · Cited by 36
Brannigan, R. P., Walder, A., & Dove, A. P. (2014) · Journal of Polymer Science Part A: Polymer Chemistry · doi:10.1002/pola.27246 · Cited by 21
Metadata
- Authors
- Jenkins, M. J., & Harrison, K. L.
- Venue
- Polymers for Advanced Technologies
- Publisher
- Wiley
- Published
- 2006-06
- Volume
- 17
- Issue
- 6
- Pages
- 474-478
- ISSN
- 1042-7147 (ISSN-L)
- 1099-1581
- OpenAlex
- W2112650492
- Cited by
- 172
- References
- 2
- FWCI
- 2.77
- Type
- journal article
- Language
- en
- Open access
- closed
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- Jenkins, M. J., & Harrison, K. L. (2006). The effect of molecular weight on the crystallization kinetics of polycaprolactone. Polymers for Advanced Technologies. https://doi.org/10.1002/pat.733
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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