Crystallization and thermal characterization of biodegradable tri-block copolymers and poly(ester-urethane)s based on PCL and PLLA
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An interesting approach to tune the mechanical and thermal performance of PLA, such as thermally-activated shape-memory behaviour, is to copolymerize it with PCL in the form of tri-block polymers based on PLLAb-PCLb-PLLA to further obtain the corresponding poly(ester-urethane) (PU).
“An interesting approach to tune the mechanical and thermal performance of PLA, such as thermally-activated shape-memory behaviour, is to copolymerize it with PCL in the form of tri-block polymers based on PLLAb -PCLb -PLLA to further obtain the corresponding poly(ester-urethane) (PU) [6-9].”
From Biodegradable poly(ester-urethane) incorporated with catechin with shape memory and antioxidant activity for food packaging (2017) · cites this paper as [8]
PLLA degrades at a lower temperature than PCL.
“This is because PLLA degrades at lower temperature with respect to PCL.37”
From Crystallization, thermal and mechanical properties of stereocomplexed poly(lactide) with flexible PLLA/PCL multiblock copolymer (2022) · cites this paper as [46]
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Jing, Z., Huang, X., Liu, X., Liao, M., & Li, Y. (2023) · Polymer International · doi:10.1002/pi.6445 · Cited by 11 · see citing works
- Authors
- Navarro-Baena, I., Kenny, J. M., & Peponi, L.
- Affiliations
- University of Perugia (IT)
- Consejo Superior de Investigaciones Científicas (ES)
- Corresponding author
- Peponi, Laura
- Venue
- Polymer Degradation and Stability
- Publisher
- Elsevier BV
- Published
- 2014-10
- Volume
- 108
- Pages
- 140-150
- ISSN
- 0141-3910 (ISSN-L)
- OpenAlex
- W2057116897
- Cited by
- 36
- References
- 47
- Citations by year
- 2026: 2 · 2025: 2 · 2024: 2 · 2023: 1 · 2022: 6 · 2021: 2 · 2020: 3 · 2019: 2 · 2017: 5 · 2016: 2 · 2015: 6 · 2014: 3
- FWCI
- 2.02
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Polymer Degradation and Stability (publishedVersion)
- DIGITAL.CSIC (Spanish National Research Council (CSIC)) (submittedVersion)
- Funders
- Consejo Superior de Investigaciones Científicas
- Ministerio de Ciencia e Innovación (MAT2010-21494-C03-03)
- Faculty of Science and Engineering, University of Manchester
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Physical Sciences › Materials Science › Materials Chemistry › Block Copolymer Self-Assembly
- Keywords
- biodegradable polymers, triblock copolymers, polycaprolactone, polylactic acid, crystallization kinetics, Avrami equation, thermal stability, thermal degradation, ring-opening polymerization, hexamethylene diisocyanate, crystallinity, block copolymer composition
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