Toughening and Self‐Healing of Carbon Fiber/Epoxy Composites Interleaved With Meltable/Non‐Meltable Polyamide Nanofiber Veils
Abstract
In this study, the effect of interleaved thermoplastic nanofiber veils on the toughening and self‐healing properties of composite laminates was investigated. To achieve this, electrospun meltable and non‐meltable thermoplastic veils and their combinations were introduced into the carbon fiber/epoxy composite laminates and subjected to a series of tests alongside virgin specimens. The results showed that the mode I fracture toughness (G IC ) of the laminate with interleaved hybrid thermoplastic veils was significantly improved by 85.7%, and the healing efficiency of the laminate under thermal excitation for short beam shear damage and drop hammer impact damage was 91.7% and 36.2%, respectively, which could not be achieved solely by inserting meltable or non‐meltable thermoplastic veils. Furthermore, the addition of low‐melting veils significantly enhanced the compatibility of the thermoplastic nanofibers with the epoxy resin matrix, thus minimizing the negative effect of thermoplastic interleaves on the interlaminar shear strength and flexural strength of the laminates.
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Fibre reinforced composites in aircraft construction
Soutis, C. (2005) · Progress in Aerospace Sciences · doi:10.1016/j.paerosci.2005.02.004 · Cited by 1,318 · see citing works
Mechanically robust, readily repairable polymers via tailored noncovalent cross-linking
Yanagisawa, Y., Nan, Y., Okuro, K., & Aida, T. (2017) · Science · doi:10.1126/science.aam7588 · Cited by 1,077 · see citing works
Past, present and future prospective of global carbon fibre composite developments and applications
Zhang, J., Lin, G., Vaidya, U., et al. (2022) · Composites Part B Engineering · doi:10.1016/j.compositesb.2022.110463 · Cited by 1,035 · see citing works
Current status of carbon fibre and carbon fibre composites recycling
Zhang, J., Chevali, V. S., Wang, H., et al. (2020) · Composites Part B Engineering · doi:10.1016/j.compositesb.2020.108053 · Cited by 869 · see citing works
Beckermann, G. W., & Pickering, K. L. (2015) · Composites Part A Applied Science and Manufacturing · doi:10.1016/j.compositesa.2015.01.028 · Cited by 275 · see citing works
Zhang, J., Lin, T., & Wang, X. (2010) · Composites Science and Technology · doi:10.1016/j.compscitech.2010.06.019 · Cited by 185 · see citing works
Jagadeesh, P., Rangappa, S. M., Siengchin, S., Puttegowda, M., Thiagamani, S. M. K., Rajeshkumar, G., Mohit, H., Oladijo, O. P., Fiore, V., & Moure, M. M. (2022) · Polymer Composites · doi:10.1002/pc.27000 · Cited by 168 · see citing works
Polyethylene-co-methacrylic acid healing agents for mendable epoxy resins
Meure, S., Wu, D. Y., & Furman, S. (2009) · Acta Materialia · doi:10.1016/j.actamat.2009.05.032 · Cited by 145 · see citing works
Daelemans, L., van der Heijden, S., Baere, I. D., et al. (2016) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.6b02247 · Cited by 143 · see citing works
Kim, K., Kim, D.-K., Kim, B., et al. (2016) · Composites Part B Engineering · doi:10.1016/j.compositesb.2016.12.009 · Cited by 118 · see citing works
Pingkarawat, K., Wang, C., Varley, R. J., & Mouritz, A. P. (2012) · Composites Part A Applied Science and Manufacturing · doi:10.1016/j.compositesa.2012.03.010 · Cited by 106 · see citing works
Aljarrah, M., & Abdelal, N. (2019) · Composites Part B Engineering · doi:10.1016/j.compositesb.2019.01.065 · Cited by 102 · see citing works
Quan, D., Bologna, F., Scarselli, G., et al. (2019) · Composites Part A Applied Science and Manufacturing · doi:10.1016/j.compositesa.2019.105642 · Cited by 100 · see citing works
Interlayer toughening of composite materials
Tsotsis, T. K. (2008) · Polymer Composites · doi:10.1002/pc.20535 · Cited by 94 · see citing works
Mechanical performance of laminated composites incorporated with nanofibrous membranes
Liu, L., Huang, Z., He, C., et al. (2006) · Materials Science and Engineering A · doi:10.1016/j.msea.2006.07.064 · Cited by 83 · see citing works
Healing of carbon fibre–epoxy composites using thermoplastic additives
Pingkarawat, K., Bhat, T., Craze, D. A., Wang, C., Varley, R. J., & Mouritz, A. P. (2013) · Polymer Chemistry · doi:10.1039/c3py00459g · Cited by 79 · see citing works
Daelemans, L., Cohades, A., Meireman, T., et al. (2017) · Materials & Design · doi:10.1016/j.matdes.2017.12.045 · Cited by 73 · see citing works
The effect of PVDF nanofibers on mode-I fracture toughness of composite materials
Saghafi, H., Brugo, T. M., Minak, G., et al. (2014) · Composites Part B Engineering · doi:10.1016/j.compositesb.2014.12.015 · Cited by 71 · see citing works
Quan, D., Alderliesten, R. C., Dransfeld, C. A., et al. (2020) · Composite Structures · doi:10.1016/j.compstruct.2020.112699 · Cited by 71 · see citing works
Mechanical properties of mendable composites containing self-healing thermoplastic agents
Pingkarawat, K., Wang, C. H., Varley, R. J., & Mouritz, A. P. (2014) · Composites Part A: Applied Science and Manufacturing · doi:10.1016/j.compositesa.2014.05.015 · Cited by 62 · see citing works
Quan, D., Deegan, B., Alderliesten, R. C., et al. (2020) · Materials & Design · doi:10.1016/j.matdes.2020.108781 · Cited by 62 · see citing works
do Nascimento, A. A., Fernandez, F. F., da Silva, F. S., Ferreira, E. P. D. C., Melo, J. D. D., & Barbosa, A. P. C. (2020) · Composites Part A Applied Science and Manufacturing · doi:10.1016/j.compositesa.2020.106016 · Cited by 48 · see citing works
Chen, B., Cai, H., Mao, C., Gan, Y., & Wei, Y. (2022) · Polymer Composites · doi:10.1002/pc.26605 · Cited by 46 · see citing works
Self-citationGao, Y., Liu, L., Wu, Z., & Zhong, Z. (2019) · Composites Part A Applied Science and Manufacturing · doi:10.1016/j.compositesa.2019.105510 · Cited by 39 · see citing works
Liu, D., Li, G., Li, B., et al. (2016) · Composites Part A Applied Science and Manufacturing · doi:10.1016/j.compositesa.2016.01.015 · Cited by 38 · see citing works
Self-citationEun, J. H., Kim, D. H., & Lee, J. S. (2020) · Composites Part A Applied Science and Manufacturing · doi:10.1016/j.compositesa.2020.105987 · Cited by 38 · see citing works
Damage recovery after impact in E-glass reinforced poly(ε-caprolactone)/epoxy blends
Cohades, A., & Michaud, V. J. (2017) · Composite Structures · doi:10.1016/j.compstruct.2017.08.050 · Cited by 37 · see citing works
Quan, D., Yue, D., Ma, Y., et al. (2022) · Composites Communications · doi:10.1016/j.coco.2022.101230 · Cited by 36 · see citing works
Evaluation of self-healing capability of a polycaprolactone interphase in epoxy/glass composites
Simonini, L., Mahmood, H., Dorigato, A., & Pegoretti, A. (2023) · Composites Part A Applied Science and Manufacturing · doi:10.1016/j.compositesa.2023.107539 · Cited by 36 · see citing works
Nash, N. H., Young, T. M., & Stanley, W. F. (2016) · Composite Structures · doi:10.1016/j.compstruct.2016.05.086 · Cited by 33 · see citing works
Yang, T., Hu, L., Xiong, X., et al. (2021) · Polymer Composites · doi:10.1002/pc.26223 · Cited by 26 · see citing works
Che, Z., Li, M., Wang, S., et al. (2022) · Polymer Composites · doi:10.1002/pc.26593 · Cited by 25 · see citing works
Self-citationFracture resistance of in-situ healed CFRP composite using thermoplastic healants
Jony, B., Roy, S., & Mulani, S. B. (2020) · Materials Today Communications · doi:10.1016/j.mtcomm.2020.101067 · Cited by 24 · see citing works
Poly(ethylene-co-methacrylic acid) coated carbon fiber for self-healing composites
Peñas-Caballero, M., Chemello, E., Grande, A. M., Santana, M. H., Verdejo, R., & López-Manchado, M. Á. (2023) · Composites Part A Applied Science and Manufacturing · doi:10.1016/j.compositesa.2023.107537 · Cited by 24 · see citing works
Toughening Behavior of Carbon/Epoxy Laminates Interleaved by PSF/PVDF Composite Nanofibers
Saghafi, H., Palazzetti, R., Heidary, H., et al. (2020) · Applied Sciences · doi:10.3390/app10165618 · Cited by 20 · see citing works
do Nascimento, A. A., Trappe, V., Melo, J. D. D., & Barbosa, A. P. C. (2022) · Polymer Testing · doi:10.1016/j.polymertesting.2022.107863 · Cited by 10 · see citing works
Vidal, J., Hornero, C., Garcia, R., et al. (2023) · Polymer Composites · doi:10.1002/pc.27636 · Cited by 8 · see citing works
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Perin, D., Fredi, G., Russo, P., Pegoretti, A., & Dorigato, A. (2025) · Composites Part A Applied Science and Manufacturing · doi:10.1016/j.compositesa.2025.109393 · Cited by 2 · see citing works
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- Authors
- Cai, H., Li, M., Gan, Y., Xiao, H., Wang, K., & Luan, Y.
- Affiliations
- Wuhan University of Technology (CN)
- Wuhan Technical College of Communications (CN)
- Corresponding author
- Cai, Haopeng
- Venue
- Polymer Composites
- Publisher
- Wiley
- Published
- 2025-05-26
- Volume
- 46
- Issue
- 15
- Pages
- 14148-14157
- ISSN
- 0272-8397 (ISSN-L)
- 1548-0569
- OpenAlex
- W4410732679
- Semantic Scholar
- 59f958c0254c84f4bc5bda89771634315c4ba0b2
- Cited by
- 2
- References
- 37
- Citations by year
- 2026: 1 · 2025: 1
- FWCI
- 0.66
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Polymer Composites (publishedVersion)
- Topics
- Physical Sciences › Engineering › Mechanics of Materials › Mechanical Behavior of Composites
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
- Physical Sciences › Engineering › Mechanical Engineering › Fiber-reinforced polymer composites
- Keywords
- carbon/epoxy composites, self-healing composites, toughening, electrospun nanofibers, mode I fracture toughness, thermal healing, interlaminar shear strength, flexural strength
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