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Cited by 359

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Phase continuity and inversion in polymer blends and simultaneous interpenetrating networks

Jordhamo, G. M., Manson, J. A., Sperling, L. H.·1986·Polymer Engineering & Science

Abstract

A semi‐empirical expression for predicting phase continuity and inversion in polymer blends and simultaneous interpenetrating networks (SINs) was developed and examined experimentally. A rheological model based on the volume fraction, ϕ, and viscosity, η, led to the equation as the criteria for dual phase continuity for phases 1 and 2. This relation was evaluated for two systems: a castor oil polyester‐urethane/polystyrene SIN, and a mechanical blend of polystyrene and polybutadiene. Literature data was also examined. A gradual phase inversion was found, with a region of dual phase continuity in between. While predictions of phase continuity were confirmed for the mechanical blends, they were not confirmed for the SIN system. This was probably due to rapid gelation at the point of phase inversion.

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Metadata

Authors
Jordhamo, G. M., Manson, J. A., & Sperling, L. H.
Venue
Polymer Engineering & Science
Publisher
Wiley
Published
1986-04
Volume
26
Issue
8
Pages
517-524
ISSN
  • 0032-3888 (ISSN-L)
  • 1548-2634
OpenAlex
W2151527465
Cited by
359
References
6
FWCI
4.38
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Phase continuity and inversion in polymer blends and simultaneous interpenetrating networks. https://app.cochat.ai/papers/10.1002/pen.760260802
The paper
Jordhamo, G. M., Manson, J. A., & Sperling, L. H. (1986). Phase continuity and inversion in polymer blends and simultaneous interpenetrating networks. Polymer Engineering & Science. https://doi.org/10.1002/pen.760260802

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.