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A study on polymer blending microrheology: Part IV. The influence of coalescence on blend morphology origination

Elmendorp, J. J., Van Der Vegt, A. K.·1986·Polymer Engineering & Science

Abstract

The influence of shear induced coalescence on the origination of morphologies in polymer blending processes is investigated both theoretically and experimentally. In the theoretical part a route is proposed to estimate the fraction of collisions between disperse phase domains in simple shear flow that result in an actual coalescence. It was shown that under polymer blending conditions this “coalescence probability” is only substantial if the polymer/polymer interfaces exhibit a high degree of mobility. In the experimental part, the phenomenon of gravity induced droplet/planar interface coalescence is utilized to show the high degree of mobility of molten polymer interfaces. Seoul experiments on the relation between domain size and disperse phase concentration in polymer blends prepared on a single screw extruder were carried out. For extremely low concentration (<½ %) the domain size could be predicted satisfactorily by means of Taylor's classical criterion for Newtonian liquids, while at higher concentration coalescence increased the average domain size manifold.

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Metadata

Authors
Elmendorp, J. J., & Van Der Vegt, A. K.
Venue
Polymer Engineering & Science
Publisher
Wiley
Published
1986-10
Volume
26
Issue
19
Pages
1332-1338
ISSN
  • 0032-3888 (ISSN-L)
  • 1548-2634
OpenAlex
W2003660444
Cited by
220
References
0
FWCI
1.95
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: A study on polymer blending microrheology: Part IV. The influence of coalescence on blend morphology origination. https://app.cochat.ai/papers/10.1002/pen.760261908
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Elmendorp, J. J., & Van Der Vegt, A. K. (1986). A study on polymer blending microrheology: Part IV. The influence of coalescence on blend morphology origination. Polymer Engineering & Science. https://doi.org/10.1002/pen.760261908

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.