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Ion ⇄ ester equilibria in the living cationic polymerization of tetrahydrofuran
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Esters of Brönsted acids (e.g., ROSO2CF3 and ROSO2F) can be used as initiators, acting as precursors for carbenium ion initiation.
“Esters of Brönsted acids (e.g., ROSO2CF3 and ROSO2F) can also be used as initiators [57 -59], whereby the covalent initiators act as precursors for a carbenium ion initiation ( vide supra ).”
From Ring-Opening Polymerization—An Introductory Review (2013) · cites this paper as [59]
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Metadata
- Authors
- Matyjaszewski, K., Kubisa, P., & Penczek, S.
- Affiliations
- Centrum Badań Molekularnych i Makromolekularnych Polskiej Akademii Nauk (PL)
- Venue
- Journal of Polymer Science: Polymer Chemistry Edition
- Publisher
- Wiley
- Published
- 1974-06
- Volume
- 12
- Issue
- 6
- Pages
- 1333-1336
- ISSN
- 0360-6376 (ISSN-L)
- 1542-9369
- OpenAlex
- W2073180353
- Cited by
- 42
- References
- 3
- Citations by year
- 2019: 1 · 2017: 1 · 2016: 2 · 2015: 3 · 2014: 1 · 2013: 2 · 2012: 2
- FWCI
- 7.10
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Polymer Science Polymer Chemistry Edition (publishedVersion)
- Topics
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer Synthesis and Characterization
- Keywords
- living cationic polymerization, tetrahydrofuran, cationic polymers, polymerization kinetics
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