Synthesis and radical ring‐opening polymerization of spiro o‐carbonates
Abstract
Abstract Syntheses and radical ring‐opening polymerization of spiro o‐carbonates(I‐IV) were investigated. magnified image These polymers were yellow powders and soluble in common organic solvents. The infrared and NMR spectra indicated that the polymers were alternate copolymers of either and carbonate containing double bonds. The polymerization mechanism is discussed.
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Spiro ortho esters shown in Figure 9 have been shown to polymerize, essentially quantitatively, via a radical ROP.
“The spiro ortho esters shown in Figure 9 have also been shown to polymerize, essentially quantitatively, via a radical ROP [21 -24].”
From Ring-Opening Polymerization—An Introductory Review (2013) · cites this paper as [21]
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Self-citation
- Authors
- Endo, T., & Bailey, W. J.
- Affiliations
- Tokyo Institute of Technology (JP)
- University of Maryland, College Park (US)
- Venue
- Journal of Polymer Science: Polymer Chemistry Edition
- Publisher
- Wiley
- Published
- 1975-11
- Volume
- 13
- Issue
- 11
- Pages
- 2525-2530
- ISSN
- 0360-6376 (ISSN-L)
- 1542-9369
- OpenAlex
- W2163489014
- Cited by
- 89
- References
- 6
- Citations by year
- 2025: 1 · 2024: 1 · 2022: 2 · 2021: 1 · 2020: 2 · 2019: 2 · 2018: 1 · 2017: 2 · 2016: 2 · 2015: 4 · 2014: 2 · 2013: 4 · 2012: 2
- FWCI
- 2.54
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Polymer Science Polymer Chemistry Edition (publishedVersion)
- Topics
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Keywords
- radical ring-opening polymerization, polymer synthesis, polymerization mechanism, spiro compounds
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