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Some phenomenological consequences of the Doi–Edwards theory of viscoelasticity
Abstract
Doi and Edwards have recently proposed a molecular theory for the dynamics of entangled polymer liquids based on a tube model to represent the mutual constraints on configurational rearrangement of the chains. Expressions for diffusion coefficient, plateau modulus, zero‐shear viscosity, steady‐state recoverable compliance, and terminal relaxation time can be devloped, and relations among these properties that depend only upon observable quantities can be obtained. Several such relations are derived and are compared with experimental observations.
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Citations
Cited by
Viscoelasticity and dynamics of entangled polymers
Watanabe, H. (1999) · Progress in Polymer Science · doi:10.1016/s0079-6700(99)00029-5 · Cited by 718
Quantitative theory for linear dynamics of linear entangled polymers
Likhtman, A. E., & McLeish, T. C. B. (2002) · Macromolecules · doi:10.1021/ma0200219 · Cited by 666
Fetters, L. J., Lohse, D. J., Milner, S. T., & Graessley, W. W. (1999) · Macromolecules · doi:10.1021/ma990620o · Cited by 487
Self-citationReptation and contour-length fluctuations in melts of linear polymers
Milner, S. T., & McLeish, T. C. B. (1998) · Physical Review Letters · doi:10.1103/physrevlett.81.725 · Cited by 451
Microscopic and molecular fundamentals of crazing
Kramer, E. J. (2005) · Advances in Polymer Science · doi:10.1007/bfb0024055 · Cited by 422
Metadata
- Authors
- Graessley, W. W.
- Venue
- Journal of Polymer Science: Polymer Physics Edition
- Publisher
- Wiley
- Published
- 1980-01
- Volume
- 18
- Issue
- 1
- Pages
- 27-34
- ISSN
- 0098-1273 (ISSN-L)
- 1542-9385
- OpenAlex
- W4232765869
- Cited by
- 234
- References
- 0
- FWCI
- 19.96
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Some phenomenological consequences of the Doi–Edwards theory of viscoelasticity. https://app.cochat.ai/papers/10.1002/pol.1980.180180103
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- Graessley, W. W. (1980). Some phenomenological consequences of the Doi–Edwards theory of viscoelasticity. Journal of Polymer Science: Polymer Physics Edition. https://doi.org/10.1002/pol.1980.180180103
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