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X‐ray photoelectron spectroscopic chemical state quantification of mixed nickel metal, oxide and hydroxide systems
Open accessAbstract
Quantitative chemical state X‐ray photoelectron spectroscopic analysis of mixed nickel metal, oxide, hydroxide and oxyhydroxide systems is challenging due to the complexity of the Ni 2p peak shapes resulting from multiplet splitting, shake‐up and plasmon loss structures. Quantification of mixed nickel chemical states and the qualitative determination of low concentrations of Ni(III) species are demonstrated via an approach based on standard spectra from quality reference samples (Ni, NiO, Ni(OH) 2 , NiOOH), subtraction of these spectra, and data analysis that integrates information from the Ni 2p spectrum and the O 1s spectra. Quantification of a commercial nickel powder and a thin nickel oxide film grown at 1‐Torr O 2 and 300 °C for 20 min is demonstrated. The effect of uncertain relative sensitivity factors (e.g. Ni 2.67 ± 0.54) is discussed, as is the depth of measurement for thin film analysis based on calculated inelastic mean free paths. Copyright © 2009 John Wiley & Sons, Ltd.
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Cited by
Biesinger, M. C., Payne, B. P., Grosvenor, A. P., Lau, L. W. M., Gerson, A. R., & Smart, R. S. C. (2011) · Applied Surface Science · doi:10.1016/j.apsusc.2010.10.051 · Cited by 11,640
Self-citationBiesinger, M. C. (2022) · Applied Surface Science · doi:10.1016/j.apsusc.2022.153681 · Cited by 774
Self-citationElectrochemical oxygen reduction catalysed by Ni3(hexaiminotriphenylene)2
Miner, E. M., Fukushima, T., Sheberla, D., Sun, L., Surendranath, Y., & Dincă, M. (2016) · Nature Communications · doi:10.1038/ncomms10942 · Cited by 710
Effect of interlayer anions on [NiFe]-LDH nanosheet water oxidation activity
Hunter, B. M., Hieringer, W., Winkler, J. R., Gray, H. B., & Müller, A. M. (2016) · Energy & Environmental Science · doi:10.1039/c6ee00377j · Cited by 616
Yu, X., Zhao, J., Zheng, L.-R., Tong, Y., Zhang, M., Xu, G., Li, C., Ma, J., & Shi, G. (2018) · ACS Energy Letters · doi:10.1021/acsenergylett.7b01103 · Cited by 357
Metadata
- Authors
- Biesinger, M. C., Payne, B. P., Lau, L. W. M., Gerson, A., & Smart, R. S. C.
- Venue
- Surface and Interface Analysis
- Publisher
- Wiley
- Published
- 2009-01-28
- Volume
- 41
- Issue
- 4
- Pages
- 324-332
- ISSN
- 0142-2421 (ISSN-L)
- 1096-9918
- OpenAlex
- W2108953022
- Cited by
- 1,826
- References
- 0
- FWCI
- 6.79
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Biesinger, M. C., Payne, B. P., Lau, L. W. M., Gerson, A., & Smart, R. S. C. (2009). X‐ray photoelectron spectroscopic chemical state quantification of mixed nickel metal, oxide and hydroxide systems. Surface and Interface Analysis. https://doi.org/10.1002/sia.3026
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