Cited by 1,199Electron and X-Ray Spectroscopy TechniquesX-ray Spectroscopy and Fluorescence AnalysisIon-surface interactions and analysis

Resolving ruthenium: XPS studies of common ruthenium materials

Morgan, David J.·2015·Surface and Interface Analysis

Abstract

X‐ray photoelectron spectroscopy (XPS) utilising monochromatic Al K α radiation has been employed to study metallic ruthenium and the catalytically and technologically important ruthenium compounds RuO 2 , RuCl 3 , Ru(NO)(NO 3 ) 3 and Ru(AcAc) 3 . The results improve on the accuracy of already published Ru(3d) binding energies, expand known Ru(3p) binding energies and also report spin‐orbit splitting for the core levels. For RuO 2 , the difference between anhydrous and hydrated samples is explored, and the effect on curve fitting such spectra is discussed. Analysis of RuCl 3 has allowed, for the first time, the positive identification of Ru(OH) 3 by XPS. Copyright © 2015 John Wiley & Sons, Ltd.

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Crossref · 10.1002/sia.5852

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Authors
Morgan, D. J.
Affiliations
Cardiff University (GB)
Corresponding author
Morgan, David J.
Venue
Surface and Interface Analysis
Publisher
Wiley
Published
2015-09-22
Volume
47
Issue
11
Pages
1072-1079
ISSN
  • 0142-2421 (ISSN-L)
  • 1096-9918
OpenAlex
W2137525974
Cited by
1,199
References
72
Citations by year
2026: 154 · 2025: 181 · 2024: 168 · 2023: 160 · 2022: 135 · 2021: 103 · 2020: 110 · 2019: 93 · 2018: 52 · 2017: 22 · 2016: 19 · 2015: 2
FWCI
12.30
Type
journal article
Language
en
Open access
closed
Locations
  • Surface and Interface Analysis (publishedVersion)
  • ORCA Online Research @Cardiff (Cardiff University) (submittedVersion)
Funders
Cardiff Catalysis Institute
Topics
  • Physical Sciences › Materials Science › Surfaces, Coatings and Films › Electron and X-Ray Spectroscopy Techniques
  • Physical Sciences › Physics and Astronomy › Radiation › X-ray Spectroscopy and Fluorescence Analysis
  • Physical Sciences › Engineering › Computational Mechanics › Ion-surface interactions and analysis
Keywords
ruthenium, ruthenium oxide, RuCl3, ruthenium nitrosyl complexes, spin-orbit splitting

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