Facile Aqueous‐Phase Synthesis of Uniform Palladium Nanoparticles of Various Shapes and Sizes
Abstract
Uniform palladium nanoparticles of various sizes and shapes are synthesized via a simple aqueous-phase reaction between Pd2+ ions and PEOx–PPOy–PEOx triblock copolymers; the size and shape are controlled by varying reaction conditions such as the pH value (see image). The palladium nanoparticles showed high catalytic activities for Suzuki cross-coupling reactions.
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PEO segments in PEO-PPO-PEO triblock copolymer were able to reduce metal ions, forming cavities (pseudocrown ethers) binding PdCl4 2- from starting precursors; bound PdCl4 2- ions might then be reduced via oxidation of oxyethylene segments by the metal center.
“Shao's group believed that PEO segments in the PEO-PPO-PEO triblock copolymer were able to reduce metal ions, thus forming cavities (pseudocrown ethers) binding PdCl 42-from the starting precursors: the bound PdCl 4 2-ions might then be reduced via oxidation of the oxyethylene segments by the metal center.311,312”
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- Authors
- Piao, Y., Jang, Y., Shokouhimehr, M., Lee, I. S., & Hyeon, T.
- Affiliations
- Seoul National University (KR)
- Kyung Hee University (KR)
- Venue
- Small
- Publisher
- Wiley
- Published
- 2007-01-29
- Volume
- 3
- Issue
- 2
- Pages
- 255-260
- ISSN
- 1613-6810 (ISSN-L)
- 1613-6829
- OpenAlex
- W2148542582
- Cited by
- 173
- References
- 88
- Citations by year
- 2026: 2 · 2025: 4 · 2024: 3 · 2023: 5 · 2022: 5 · 2021: 8 · 2020: 12 · 2019: 10 · 2018: 3 · 2017: 11 · 2016: 5 · 2015: 11 · 2014: 11 · 2013: 13 · 2012: 11
- FWCI
- 7.02
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Small (publishedVersion)
- PubMed (publishedVersion)
- Seoul National University Open Repository (Seoul National University) (submittedVersion)
- Topics
- Physical Sciences › Chemistry › Organic Chemistry › Catalytic Cross-Coupling Reactions
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Physical Sciences › Chemistry › Organic Chemistry › Nanomaterials for catalytic reactions
- Keywords
- palladium nanoparticles, aqueous synthesis, triblock copolymers, PEO-PPO-PEO, nanoparticle size control, nanoparticle shape control, pH effect, Suzuki coupling, catalytic activity, nanoparticle templating
- MeSH terms
- Colloids, Crystallization, Materials Testing, Molecular Conformation, Palladium, Particle Size, Solutions, Surface Properties, Water, Nanotechnology, Phase Transition, Macromolecular Substances, Nanostructures
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