Facile Aqueous‐Phase Synthesis of Uniform Palladium Nanoparticles of Various Shapes and Sizes
Abstract
Uniform palladium nanoparticles of various sizes and shapes are synthesized via a simple aqueous-phase reaction between Pd2+ ions and PEOx–PPOy–PEOx triblock copolymers; the size and shape are controlled by varying reaction conditions such as the pH value (see image). The palladium nanoparticles showed high catalytic activities for Suzuki cross-coupling reactions.
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
PEO segments in PEO-PPO-PEO triblock copolymer were able to reduce metal ions, forming cavities (pseudocrown ethers) binding PdCl4 2- from starting precursors; bound PdCl4 2- ions might then be reduced via oxidation of oxyethylene segments by the metal center.
“Shao's group believed that PEO segments in the PEO-PPO-PEO triblock copolymer were able to reduce metal ions, thus forming cavities (pseudocrown ethers) binding PdCl 42-from the starting precursors: the bound PdCl 4 2-ions might then be reduced via oxidation of the oxyethylene segments by the metal center.311,312”
Cites
Daniel, M., & Astruc, D. (2003) · Chemical Reviews · doi:10.1021/cr030698+ · Cited by 12,486 · see citing works
Triblock Copolymer Syntheses of Mesoporous Silica with Periodic 50 to 300 Angstrom Pores
Zhao, D., Feng, J., Huo, Q., Melosh, N. A., Fredrickson, G. H., Chmelka, B. F., & Stucky, G. D. (1998) · Science · doi:10.1126/science.279.5350.548 · Cited by 11,761 · see citing works
Chemistry and Properties of Nanocrystals of Different Shapes
Burda, C., Chen, X., Narayanan, R., & El-Sayed, M. A. (2005) · Chemical Reviews · doi:10.1021/cr030063a · Cited by 7,230 · see citing works
Recent Advances in the Liquid-Phase Syntheses of Inorganic Nanoparticles
Cushing, B. L., Kolesnichenko, V. L., & O’Connor, C. J. (2004) · Chemical Reviews · doi:10.1021/cr030027b · Cited by 2,920 · see citing works
Crooks, R. M., Zhao, M., Sun, L., Chechik, V., & Yeung, L. K. (2000) · Accounts of Chemical Research · doi:10.1021/ar000110a · Cited by 2,117 · see citing works
Alexandridis, P., & Hatton, T. A. (1995) · Colloids and Surfaces A Physicochemical and Engineering Aspects · doi:10.1016/0927-7757(94)03028-x · Cited by 1,923 · see citing works
Chemical synthesis of magnetic nanoparticles
Hyeon, T. (2002) · Chemical Communications · doi:10.1039/b207789b · Cited by 1,581 · see citing works
Self-citationPluronic® block copolymers as novel polymer therapeutics for drug and gene delivery
Kabanov, A. V., Batrakova, E. V., & Alakhov, V. Y. (2002) · Journal of Controlled Release · doi:10.1016/s0168-3659(02)00009-3 · Cited by 1,474 · see citing works
Yang, P., Zhao, D., Margolese, D. I., Chmelka, B. F., & Stucky, G. D. (1999) · Chemistry of Materials · doi:10.1021/cm990185c · Cited by 1,135 · see citing works
(2010) · Wiley eBooks · doi:10.1002/9783527631544 · Cited by 1,017 · see citing works
Gold Nanocages: Bioconjugation and Their Potential Use as Optical Imaging Contrast Agents
Chen, J., Saeki, F., Wiley, B. J., Cang, H., Cobb, M. J., Li, Z., Au, L., Zhang, H., Kimmey, M. B., Li, X. D., et al. (2005) · Nano Letters · doi:10.1021/nl047950t · Cited by 977 · see citing works
Nanoparticles from theory to application
Schmid, G. 1. (2004) · Cited by 844 · see citing works
The preparation of monodisperse colloidal metal particles from microemulsions
Boutonnet, M., Kizling, J., Stenius, P. J., & Maire, G. (1982) · Colloids and Surfaces · doi:10.1016/0166-6622(82)80079-6 · Cited by 792 · see citing works
Xiong, Y., McLellan, J. M., Chen, J., Yin, Y., Li, Z., & Younan Xia, A. (2005) · Journal of the American Chemical Society · doi:10.1021/ja056498s · Cited by 668 · see citing works
Im, S. H., Lee, Y. T., Wiley, B. J., et al. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200462208 · Cited by 658 · see citing works
One‐Nanometer‐Scale Size‐Controlled Synthesis of Monodisperse Magnetic Iron Oxide Nanoparticles
Park, J., Lee, E., Hwang, N., Kang, M., Kim, S. C., Hwang, Y., Park, J., Noh, H.-J., Kim, J., Park, J., et al. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200461665 · Cited by 652 · see citing works
Self-citationLigand-free Heck reactions using low Pd-loading
Reetz, M. T., & de Vries, J. G. (2004) · Chemical Communications · doi:10.1039/b406719n · Cited by 644 · see citing works
Nanoparticles and Nanostructured Films
(1998) · Wiley eBooks · doi:10.1002/9783527612079 · Cited by 634 · see citing works
Synthesis of copper metallic clusters using reverse micelles as microreactors
Lisiecki, I., & Pileni, M. P. (1993) · Journal of the American Chemical Society · doi:10.1021/ja00063a006 · Cited by 573 · see citing works
Single-Phase and Gram-Scale Routes toward Nearly Monodisperse Au and Other Noble Metal Nanocrystals
Jana, N. R., & Peng, X. (2003) · Journal of the American Chemical Society · doi:10.1021/ja038219b · Cited by 555 · see citing works
Washio, I., Xiong, Y., Yin, Y., et al. (2006) · Advanced Materials · doi:10.1002/adma.200600675 · Cited by 523 · see citing works
Block copolymer-templated mesoporous oxides
Soler‐Illia, G. J. A. A., Crepaldi, E. L., Grosso, D., & Sánchez, C. (2003) · Current Opinion in Colloid & Interface Science · doi:10.1016/s1359-0294(03)00002-5 · Cited by 501 · see citing works
Son, S. U., Jang, Y., Park, J., Na, H. B., Park, H. M., Yun, H. J., Lee, J., & Hyeon, T. (2004) · Journal of the American Chemical Society · doi:10.1021/ja039757r · Cited by 489 · see citing works
Self-citationXiong, Y., Chen, J., Wiley, B. J., Younan Xia, A., Aloni, S., & Yin, Y. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0513741 · Cited by 451 · see citing works
Suzuki Cross-Coupling Reactions Catalyzed by Palladium Nanoparticles in Aqueous Solution
Li, Y., Hong, X. M., Collard, D. M., & El‐Sayed, M. A. (2000) · Organic Letters · doi:10.1021/ol0061687 · Cited by 447 · see citing works
Li, Y., & El‐Sayed, M. A. (2001) · The Journal of Physical Chemistry B · doi:10.1021/jp010904m · Cited by 441 · see citing works
Polyol Synthesis of Platinum Nanoparticles: Control of Morphology with Sodium Nitrate
Herricks, T., Chen, J., & Younan Xia, A. (2004) · Nano Letters · doi:10.1021/nl048570a · Cited by 437 · see citing works
Synthesis of Monodisperse Palladium Nanoparticles
Kim, S., Park, J., Jang, Y., et al. (2003) · Nano Letters · doi:10.1021/nl0343405 · Cited by 422 · see citing works
Self-citationXiong, Y., Chen, J., Wiley, B. J., Younan Xia, A., Yin, Y., & Li, Z.-Y. (2005) · Nano Letters · doi:10.1021/nl0508826 · Cited by 420 · see citing works
Lee, Y., Lee, J., Bae, C. J., Park, J. ‐., Noh, H. ‐., Park, J. ‐., & Hyeon, T. (2005) · Advanced Functional Materials · doi:10.1002/adfm.200400187 · Cited by 419 · see citing works
Self-citationNanoparticles in Energy Technology: Examples from Electrochemistry and Catalysis
Raimondi, F., Scherer, G. G., Kötz, R., & Wokaun, A. J. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200460466 · Cited by 381 · see citing works
Controlled Synthesis of 2-D and 3-D Dendritic Platinum Nanostructures
Song, Y., Yang, Y. T., Medforth, C. J., Pereira, E., Singh, A. K., Xu, H., Jiang, Y., Brinker, C. J., van Swol, F., & Shelnutt, J. A. (2003) · Journal of the American Chemical Society · doi:10.1021/ja037474t · Cited by 378 · see citing works
Effect of Pd Nanoparticle Size on the Catalytic Hydrogenation of Allyl Alcohol
Wilson, O. M., Knecht, M. R., García-Martínez, J. C., & Crooks, R. M. (2006) · Journal of the American Chemical Society · doi:10.1021/ja058217m · Cited by 372 · see citing works
Quasicubic α-Fe2O3 Nanoparticles with Excellent Catalytic Performance
Zheng, Y., Cheng, Y., Wang, Y., et al. (2006) · The Journal of Physical Chemistry B · doi:10.1021/jp056617q · Cited by 350 · see citing works
Reetz, M. T., Helbig, W., Quaiser, S. A., Stimming, U., Breuer, N., & Vogel, R. (1995) · Science · doi:10.1126/science.267.5196.367 · Cited by 345 · see citing works
Sakai, T., & Alexandridis, P. (2005) · The Journal of Physical Chemistry B · doi:10.1021/jp046221z · Cited by 313 · see citing works
Sakai, T., & Alexandridis, P. (2004) · Langmuir · doi:10.1021/la049514s · Cited by 300 · see citing works
Hoppe, C. E., Lazzari, M., Pardiñas-Blanco, I., & López-Quintela, M. A. (2006) · Langmuir · doi:10.1021/la060885d · Cited by 298 · see citing works
Bimetallic Palladium−Platinum Dendrimer-Encapsulated Catalysts
Scott, R. W. J., Datye, A. K., & Crooks, R. M. (2003) · Journal of the American Chemical Society · doi:10.1021/ja034176n · Cited by 288 · see citing works
Control of the Shape of Copper Metallic Particles by Using a Colloidal System as Template
Tánori, J., & Pileni, M. P. (1997) · Langmuir · doi:10.1021/la9606097 · Cited by 274 · see citing works
Formation of Metal Particles in Aqueous Solutions by Reactions of Metal Complexes with Polymers
Longenberger, L., & Mills, G. (1995) · The Journal of Physical Chemistry · doi:10.1021/j100002a001 · Cited by 272 · see citing works
García-Martínez, J. C., Lezutekong, R., & Crooks, R. M. (2005) · Journal of the American Chemical Society · doi:10.1021/ja042479r · Cited by 258 · see citing works
Bradley, J. S., Tesche, B., Busser, W., Maase, M., & Reetz, M. T. (2000) · Journal of the American Chemical Society · doi:10.1021/ja992409y · Cited by 257 · see citing works
Synthesis of Porous Platinum Nanoparticles
Teng, X., Liang, X., Maksimuk, S., & Yang, H. (2005) · Small · doi:10.1002/smll.200500244 · Cited by 250 · see citing works
Nemamcha, A., Rehspringer, J., & Khatmi, D. (2005) · The Journal of Physical Chemistry B · doi:10.1021/jp0535801 · Cited by 247 · see citing works
Son, S. U., Jang, Y., Yoon, K. Y., et al. (2004) · Nano Letters · doi:10.1021/nl049519+ · Cited by 235 · see citing works
Self-citationEnhanced CO Tolerance for Hydrogen Activation in Au−Pt Dendritic Heteroaggregate Nanostructures
Zhou, S., McIlwrath, K., Jackson, G. S., & Eichhorn, B. W. (2006) · Journal of the American Chemical Society · doi:10.1021/ja056924+ · Cited by 227 · see citing works
(2001) · Elsevier eBooks · doi:10.1016/b978-0-444-89569-1.x5016-7 · Cited by 221 · see citing works
Radial Anisotropic Growth of Rhodium Nanoparticles
Hoefelmeyer, J. D., Niesz, K., Somorjai, G. A., & Tilley, T. D. (2005) · Nano Letters · doi:10.1021/nl048100g · Cited by 208 · see citing works
Heterogeneous Seeded Growth: A Potentially General Synthesis of Monodisperse Metallic Nanoparticles
Yu, H., Gibbons, P. C., Kelton, K. F., & Buhro, W. E. (2001) · Journal of the American Chemical Society · doi:10.1021/ja016529t · Cited by 208 · see citing works
Ishii, T., Otsuka, H., Kataoka, K., & Nagasaki, Y. (2003) · Langmuir · doi:10.1021/la035653i · Cited by 196 · see citing works
Redox-Controlled Size-Selective Fabrication of Nanostructured Transition Metal Colloids
Reetz, M. T., & Maase, M. (1999) · Advanced Materials · doi:10.1002/(sici)1521-4095(199906)11:9 · Cited by 196 · see citing works
Li, J., & Liu, W. (2004) · Organic Letters · doi:10.1021/ol048907f · Cited by 176 · see citing works
One‐Nanometer‐Scale Size‐Controlled Synthesis of Monodisperse Magnetic Iron Oxide Nanoparticles
Park, J., Lee, E., Hwang, N., Kang, M., Kim, S. C., Hwang, Y., Park, J., Noh, H., Kim, J., Park, J., et al. (2005) · Angewandte Chemie · doi:10.1002/ange.200461665 · Cited by 175 · see citing works
Self-citationA New Method for the Preparation of Nanostructured Metal Clusters
Reetz, M. T., & Quaiser, S. A. (1995) · Angewandte Chemie International Edition in English · doi:10.1002/anie.199522401 · Cited by 164 · see citing works
Zettsu, N., McLellan, J. M., Wiley, B. J., Yin, Y., Li, Z., & Younan Xia, A. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200503174 · Cited by 153 · see citing works
McLachlan, F., Mathews, C. J., Smith, P. J., et al. (2003) · Organometallics · doi:10.1021/om034075y · Cited by 153 · see citing works
Sulfide-Arrested Growth of Gold Nanorods
Zweifel, D. A., & Wei, A. (2005) · Chemistry of Materials · doi:10.1021/cm0506858 · Cited by 149 · see citing works
Lisiecki, I., & Pileni, M. P. (2003) · Langmuir · doi:10.1021/la0301386 · Cited by 145 · see citing works
High-Yield Solvothermal Formation of Magnetic CoPt Alloy Nanowires
Zhang, Z., Blom, D. A., Gai, Z., Thompson, J. R., Shen, J., & Dai, S. (2003) · Journal of the American Chemical Society · doi:10.1021/ja035185z · Cited by 138 · see citing works
Park, J., Koo, B., Hwang, Y., Bae, C., An, K., Park, J., Park, H. M., & Hyeon, T. (2004) · Angewandte Chemie International Edition · doi:10.1002/anie.200353562 · Cited by 136 · see citing works
Self-citationIm, S. H., Lee, Y. T., Wiley, B. J., et al. (2005) · Angewandte Chemie · doi:10.1002/ange.200462208 · Cited by 136 · see citing works
Rapoport, N. Y., Herron, J. N., Pitt, W. G., & Pitina, L. (1999) · Journal of Controlled Release · doi:10.1016/s0168-3659(98)00149-7 · Cited by 123 · see citing works
Facile Synthesis of Morphology-Controlled Platinum Nanocrystals
Zhong, X., Feng, Y., Lieberwirth, I., & Knoll, W. (2006) · Chemistry of Materials · doi:10.1021/cm060463p · Cited by 121 · see citing works
Polymeric pseudocrown ethers. 1. Synthesis and complexation with transition metal anions
Warshawsky, A., Kalir, R., Deshe, A., Berkovitz, H., & Patchornik, A. (1979) · Journal of the American Chemical Society · doi:10.1021/ja00509a035 · Cited by 116 · see citing works
Niesz, K., Grass, M., & Somorjai, G. A. (2005) · Nano Letters · doi:10.1021/nl051561x · Cited by 100 · see citing works
Size-Selective Synthesis of Cubooctahedral Palladium Particles Mediated by Metallomicelles
Veisz, B., & Király, Z. (2003) · Langmuir · doi:10.1021/la034146y · Cited by 99 · see citing works
Sakai, T., & Alexandridis, P. (2005) · Nanotechnology · doi:10.1088/0957-4484/16/7/006 · Cited by 97 · see citing works
Moncada, A. I., Manne, S., Tanski, J. M., & Slaughter, L. M. (2005) · Organometallics · doi:10.1021/om050786f · Cited by 95 · see citing works
Nanocrystal Templating of Silica Mesopores with Tunable Pore Sizes
Kónya, Z., Puntes, V., Kiricsi, I., Zhu, J. H., Alivisatos, A. P., & Somorjai, G. A. (2002) · Nano Letters · doi:10.1021/nl0256661 · Cited by 82 · see citing works
Synthesis of nanosize metallic and alloyed particles in ordered phases
Tánori, J., Duxin, N., Petit, C., et al. (1995) · Colloid & Polymer Science · doi:10.1007/bf00657639 · Cited by 80 · see citing works
Boutonett, M., Kizling, J., Touroude, R. A., et al. (1986) · Applied Catalysis · doi:10.1016/0166-9834(86)80013-6 · Cited by 80 · see citing works
Laser Photolysis of Silver Colloid Prepared by Citric Acid Reduction Method
Pyatenko, A., Yamaguchi, M., & Suzuki, M. (2005) · The Journal of Physical Chemistry B · doi:10.1021/jp055246a · Cited by 74 · see citing works
Wang, L., Chen, X., Zhan, J., et al. (2004) · Chemistry Letters · doi:10.1246/cl.2004.720 · Cited by 70 · see citing works
Superlattices of Platinum and Palladium Nanoparticles
Martin, J. E., Wilcoxon, J. P., Odinek, J. G., et al. (2002) · The Journal of Physical Chemistry B · doi:10.1021/jp0139944 · Cited by 70 · see citing works
Nanoscale in-plane displacement evaluation by AFM scanning and digital image correlation processing
Chang, S.-P., Wang, C. S., Xiong, C., et al. (2005) · Nanotechnology · doi:10.1088/0957-4484/16/4/002 · Cited by 61 · see citing works
O−H⋅⋅⋅PtII: Hydrogen Bond with a Strong Dispersion Component
Kozelka, J., Bergès, J., Attias, R., & Fraitag, J. (2000) · Angewandte Chemie International Edition · doi:10.1002/(sici)1521-3773(20000103)39:1 · Cited by 61 · see citing works
Controlling the Size of Magnetic Nanoparticles Using Pluronic Block Copolymer Surfactants
Lai, J., Shafi, K. V. P. M., Ulman, A., et al. (2004) · The Journal of Physical Chemistry B · doi:10.1021/jp0457702 · Cited by 59 · see citing works
Eine neue Methode zur Herstellung nanostrukturierter Metallcluster
Reetz, M. T., & Quaiser, S. A. (1995) · Angewandte Chemie · doi:10.1002/ange.19951072029 · Cited by 53 · see citing works
Zettsu, N., McLellan, J. M., Wiley, B. J., Yin, Y., Li, Z., & Younan Xia, A. (2006) · Angewandte Chemie · doi:10.1002/ange.200503174 · Cited by 50 · see citing works
Nanopartikel in der Energietechnik – Beispiele aus der Elektrochemie und Katalyse
Raimondi, F., Scherer, G. G., Kötz, R., & Wokaun, A. J. (2005) · Angewandte Chemie · doi:10.1002/ange.200460466 · Cited by 40 · see citing works
Park, J., Koo, B., Hwang, Y., Bae, C., An, K., Park, J., Park, H. M., & Hyeon, T. (2004) · Angewandte Chemie · doi:10.1002/ange.200353562 · Cited by 39 · see citing works
Self-citationMartin, M. G., Chen, B., & Siepmann, J. I. (2000) · The Journal of Physical Chemistry B · doi:10.1021/jp993212v · Cited by 33 · see citing works
Zheng, Y., Cheng, Y., Wang, Y., et al. (2005) · Journal of Crystal Growth · doi:10.1016/j.jcrysgro.2005.06.051 · Cited by 33 · see citing works
Kurihara, K., Fendler, J. H., Ravet, I., et al. (1986) · Journal of Molecular Catalysis · doi:10.1016/0304-5102(86)87011-0 · Cited by 32 · see citing works
Leben am Ende der Chromosomen: Telomere und Telomerase
Cech, T. R. (2000) · Angewandte Chemie · doi:10.1002/(sici)1521-3757(20000103)112:1 · Cited by 30 · see citing works
Local anaesthetic block copolymer system undergoing phase transition on dilution with water
Scherlund, M., Welin-Berger, K., Brodin, A. F., et al. (2001) · European Journal of Pharmaceutical Sciences · doi:10.1016/s0928-0987(01)00145-2 · Cited by 27 · see citing works
Bao, N., Shen, L., Lü, X., et al. (2003) · Chemical Physics Letters · doi:10.1016/s0009-2614(03)01115-1 · Cited by 10 · see citing works
Flagged first, then by citations
Cited by
Sorted by citations
Wang, Y.-J., Zhao, N., Fang, B., Li, H., Bi, X. T., & Wang, H. (2015) · Chemical Reviews · doi:10.1021/cr500519c · Cited by 1,267 · see citing works
Lee, Y.-W., Ko, A.-R., Han, S.-B., Kim, H.-S., & Park, K.-W. (2011) · Physical Chemistry Chemical Physics · doi:10.1039/c0cp02167a · Cited by 102 · see citing works
Zhang, G., Shao, Z.-G., Lu, W., Xiao, H., Xie, F., Qin, X., Li, J., Liu, F., & Yi, B. (2013) · The Journal of Physical Chemistry C · doi:10.1021/jp401375b · Cited by 41 · see citing works
- Authors
- Piao, Y., Jang, Y., Shokouhimehr, M., Lee, I. S., & Hyeon, T.
- Affiliations
- Seoul National University (KR)
- Kyung Hee University (KR)
- Venue
- Small
- Publisher
- Wiley
- Published
- 2007-01-29
- Volume
- 3
- Issue
- 2
- Pages
- 255-260
- ISSN
- 1613-6810 (ISSN-L)
- 1613-6829
- OpenAlex
- W2148542582
- Cited by
- 173
- References
- 88
- Citations by year
- 2026: 2 · 2025: 4 · 2024: 3 · 2023: 5 · 2022: 5 · 2021: 8 · 2020: 12 · 2019: 10 · 2018: 3 · 2017: 11 · 2016: 5 · 2015: 11 · 2014: 11 · 2013: 13 · 2012: 11
- FWCI
- 7.02
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Small (publishedVersion)
- PubMed (publishedVersion)
- Seoul National University Open Repository (Seoul National University) (submittedVersion)
- Topics
- Physical Sciences › Chemistry › Organic Chemistry › Catalytic Cross-Coupling Reactions
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Physical Sciences › Chemistry › Organic Chemistry › Nanomaterials for catalytic reactions
- Keywords
- palladium nanoparticles, aqueous synthesis, triblock copolymers, PEO-PPO-PEO, nanoparticle size control, nanoparticle shape control, pH effect, Suzuki coupling, catalytic activity, nanoparticle templating
- MeSH terms
- Colloids, Crystallization, Materials Testing, Molecular Conformation, Palladium, Particle Size, Solutions, Surface Properties, Water, Nanotechnology, Phase Transition, Macromolecular Substances, Nanostructures
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
