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Mechanical Exfoliation and Characterization of Single‐ and Few‐Layer Nanosheets of WSe2, TaS2, and TaSe2

Li, Hai, Lu, Gang, Wang, Yanlong, Yin, Zongyou, Cong, Chunxiao, He, Qiyuan, Wang, Lu, Ding, Feng, Yu, Ting, Zhang, Hua·2013·Small

Abstract

Single‐ and few‐layer transition‐metal dichalcogenide nanosheets, such as WSe 2, TaS 2, and TaSe 2, are prepared by mechanical exfoliation. A Raman microscope is employed to characterize the single‐layer (1L) to quinary‐layer (5L) WSe 2 nanosheets and WSe 2 single crystals with a laser excitation power ranging from 20 μW to 5.1 mW. Typical first‐order together with some second‐order and combinational Raman modes are observed. A new peak at around 308 cm−1 is observed in WSe 2 except for the 1L WSe 2, which might arise from interlayer interactions. Red shifting of the A1 g mode and the Raman peak around 308 cm−1 is observed from 1L to 5L WSe 2. Interestingly, hexagonal‐ and monoclinic‐structured WO 3 thin films are obtained during the local oxidation of thinner (1L–3L) and thicker (4L and 5L) WSe 2 nanosheets, while laser‐burned holes are found during the local oxidation of the WSe 2 single crystal. In addition, the characterization of TaS 2 and TaSe 2 thin layers is also conducted.

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Metadata

Authors
Li, H., Lu, G., Wang, Y., Yin, Z., Cong, C., He, Q., Wang, L., Ding, F., Yu, T., & Zhang, H.
Venue
Small
Publisher
Wiley
Published
2012-12-27
Volume
9
Issue
11
Pages
1974-1981
ISSN
  • 1613-6810 (ISSN-L)
  • 1613-6829
OpenAlex
W2167452346
Cited by
659
References
47
FWCI
13.61
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Mechanical Exfoliation and Characterization of Single‐ and Few‐Layer Nanosheets of WSe2, TaS2, and TaSe2. https://app.cochat.ai/papers/10.1002/smll.201202919
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Li, H., Lu, G., Wang, Y., Yin, Z., Cong, C., He, Q., Wang, L., Ding, F., Yu, T., & Zhang, H. (2013). Mechanical Exfoliation and Characterization of Single‐ and Few‐Layer Nanosheets of WSe2, TaS2, and TaSe2. Small. https://doi.org/10.1002/smll.201202919

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