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Graphene‐Like MoS2/Graphene Composites: Cationic Surfactant‐Assisted Hydrothermal Synthesis and Electrochemical Reversible Storage of Lithium

Huang, Guochuang, Chen, Tao, Chen, Weixiang, Wang, Zhen, Chang, Kun, Ma, Lin, Huang, Feihe, Chen, Dongyun, Lee, Jim Yang·2013·Small

Abstract

A cationic surfactant‐assisted hydrothermal route is developed for the facile synthesis of graphene‐like MoS 2/graphene (GL‐MoS 2/G) composites based on the hydrothermal reduction of Na 2 MoO 4 and graphene oxide sheets with L‐cysteine in the presence of cetyltrimethylammonium bromide (CTAB), following by annealling in N 2 atmosphere. The GL‐MoS 2/G composites are characterized by X‐ray diffraction, electron microscopy, high‐resolution transmission electron microscopy, and Raman spectroscopy. The effects of CTAB concentration on the microstructures and electrochemical performances of the composites for reversible Li+ storage are investigated. It is found that the layer number of MoS 2 sheets decreases with increasing CTAB concentration. The GL‐MoS 2 sheets in the composites are few‐layer in the case of 0.01∼0.03 mol L−1 CTAB of hydrothermal solution and single‐layer in the case of 0.05 mol L−1 CTAB. The GL‐MoS 2/G composites prepared with 0.01–0.02 mol·L−1 of CTAB solution exhibit a higher reversible capacity of 940–1020 mAh g−1, a greater cycle stability, and a higher rate capability than other samples. The exceptional electrochemical performance of GL‐MoS 2/G composites for reversible Li+ storage could be attributed to an effective integration of GL‐MoS 2 sheets and graphene that maximizes the synergistic interaction between them.

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Metadata

Authors
Huang, G., Chen, T., Chen, W., Wang, Z., Chang, K., Ma, L., Huang, F., Chen, D., & Lee, J. Y.
Venue
Small
Publisher
Wiley
Published
2013-06-14
Volume
9
Issue
21
Pages
3693-3703
ISSN
  • 1613-6810 (ISSN-L)
  • 1613-6829
OpenAlex
W2171273866
Cited by
351
References
69
FWCI
25.36
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Graphene‐Like MoS2/Graphene Composites: Cationic Surfactant‐Assisted Hydrothermal Synthesis and Electrochemical Reversible Storage of Lithium. https://app.cochat.ai/papers/10.1002/smll.201300415
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Huang, G., Chen, T., Chen, W., Wang, Z., Chang, K., Ma, L., Huang, F., Chen, D., & Lee, J. Y. (2013). Graphene‐Like MoS2/Graphene Composites: Cationic Surfactant‐Assisted Hydrothermal Synthesis and Electrochemical Reversible Storage of Lithium. Small. https://doi.org/10.1002/smll.201300415

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