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An Advanced MoS2/Carbon Anode for High-Performance Sodium-Ion Batteries

Wang, Jingjing, Luo, Chao, Gao, Tao, Langrock, Alex, Mignerey, Alice C., Wang, Chunsheng·2015·Small

Abstract

Molybdenum disulfide (MoS2 ) is a promising anode for high performance sodium-ion batteries due to high specific capacity, abundance, and low cost. However, poor cycling stability, low rate capability and unclear electrochemical reaction mechanism are the main challenges for MoS2 anode in Na-ion batteries. In this study, molybdenum disulfide/carbon (MoS2 /C) nanospheres are fabricated and used for Na-ion battery anodes. MoS2 /C nanospheres deliver a reversible capacity of 520 mAh g(-1) at 0.1 C and maintain at 400 mAh g(-1) for 300 cycles at a high current density of 1 C, demonstrating the best cycling performance of MoS2 for Na-ion batteries to date. The high capacity is attributed to the short ion and electron diffusion pathway, which enables fast charge transfer and low concentration polarization. The stable cycling performance and high coulombic efficiency (∼100%) of MoS2 /C nanospheres are ascribed to (1) highly reversible conversion reaction of MoS2 during sodiation/desodiation as evidenced by ex-situ X-ray diffraction (XRD) and (2) the formation of a stable solid electrolyte interface (SEI) layer in fluoroethylene carbonate (FEC) based electrolyte as demonstrated by fourier transform infrared spectroscopy (FTIR) measurements.

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Metadata

Authors
Wang, J., Luo, C., Gao, T., Langrock, A., Mignerey, A. C., & Wang, C.
Venue
Small
Publisher
Wiley
Published
2014-09-25
Volume
11
Issue
4
Pages
473-481
ISSN
1613-6810 (ISSN-L)
OpenAlex
W2170052611
Cited by
442
References
3
FWCI
21.76
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: An Advanced MoS2/Carbon Anode for High-Performance Sodium-Ion Batteries. https://app.cochat.ai/papers/10.1002/smll.201401521
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Wang, J., Luo, C., Gao, T., Langrock, A., Mignerey, A. C., & Wang, C. (2015). An Advanced MoS2/Carbon Anode for High-Performance Sodium-Ion Batteries. Small. https://doi.org/10.1002/smll.201401521

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