Fluoroethylene Carbonate Additives to Render Uniform Li Deposits in Lithium Metal Batteries
Abstract
Lithium (Li) metal has been considered as an important substitute for the graphite anode to further boost the energy density of Li‐ion batteries. However, Li dendrite growth during Li plating/stripping causes safety concern and poor lifespan of Li metal batteries (LMB). Herein, fluoroethylene carbonate (FEC) additives are used to form a LiF‐rich solid electrolyte interphase (SEI). The FEC‐induced SEI layer is compact and stable, and thus beneficial to obtain a uniform morphology of Li deposits. This uniform and dendrite‐free morphology renders a significantly improved Coulombic efficiency of 98% within 100 cycles in a Li | Cu half‐cell. When the FEC‐protected Li metal anode matches a high‐loading LiNi 0.5 Co 0.2 Mn 0.3 O 2 (NMC) cathode (12 mg cm −2 ), a high initial capacity of 154 mAh g −1 (1.9 mAh cm −2 ) at 180.0 mA g −1 is obtained. This LMB with conversion‐type Li metal anode and intercalation‐type NMC cathode affords an emerging energy storage system to probe the energy chemistry of Li metal protection and demonstrates the material engineering of batteries with very high energy density.
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FEC is a widely used and extensively studied additive in LIB and LMA systems because it can participate in SEI formation due to its higher reduction potential compared to nonfluorinated carbonates, enhancing its capability to form a LiF-rich SEI that protects graphite and LMA and improves cycling stability and capacity retention at room temperature.
“FEC is a widely used and extensively studied additive in LIB and LMA systems, as it can participate in SEI formation due to its higher reduction potential compared to nonfluorinated carbonates, enhancing its capability in forming a LiF-rich SEI to protect graphite and LMA, which in turn improves the cycling stability and capacity retention at RT [123,124].”
From Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries (2023) · cites this paper as [124]
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- Authors
- Zhang, X., Cheng, X., Chen, X., Yan, C., & Zhang, Q.
- Affiliations
- Tsinghua University (CN)
- Corresponding author
- Zhang, Qiang
- Venue
- Advanced Functional Materials
- Publisher
- Wiley
- Published
- 2017-01-20
- Volume
- 27
- Issue
- 10
- ISSN
- 1616-301X (ISSN-L)
- 1616-3028
- OpenAlex
- W2579562509
- Cited by
- 1,699
- References
- 0
- Citations by year
- 2026: 81 · 2025: 135 · 2024: 161 · 2023: 203 · 2022: 230 · 2021: 228 · 2020: 242 · 2019: 231 · 2018: 130 · 2017: 58
- FWCI
- 75.16
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Advanced Functional Materials (publishedVersion)
- Funders
- National Key Research and Development Program (2016YFA0202500)
- Natural Scientific Foundation of China (21422604, 21676160, 21561130151)
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced Battery Materials and Technologies
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
- Physical Sciences › Engineering › Automotive Engineering › Advanced Battery Technologies Research
- Keywords
- lithium metal batteries, fluoroethylene carbonate, electrolyte additives, lithium dendrite suppression, solid electrolyte interphase, LiF-rich SEI, lithium deposition uniformity, lithium metal anode, NCM cathode, Coulombic efficiency, high energy density
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