The DOI matches its Crossref record; 27 of the 27 references it cites were found in a registry or an index.
MOF‐Derived Hollow Co9S8 Nanoparticles Embedded in Graphitic Carbon Nanocages with Superior Li‐Ion Storage
Abstract
Novel electrode materials consisting of hollow cobalt sulfide nanoparticles embedded in graphitic carbon nanocages (HCSP⊂GCC) are facilely synthesized by a top‐down route applying room‐temperature synthesized Co‐based zeolitic imidazolate framework (ZIF‐67) as the template. Owing to the good mechanical flexibility and pronounced structure stability of carbon nanocages‐encapsulated Co 9 S 8, the as‐obtained HCSP⊂GCC exhibit superior Li‐ion storage. Working in the voltage of 1.0−3.0 V, they display a very high energy density (707 Wh kg−1), superior rate capability (reversible capabilities of 536, 489, 438, 393, 345, and 278 mA h g−1 at 0.2, 0.5, 1, 2, 5, and 10C, respectively), and stable cycling performance (≈26% capacity loss after long 150 cycles at 1C with a capacity retention of 365 mA h g−1). When the work voltage is extended into 0.01–3.0 V, a higher stable capacity of 1600 mA h g−1 at a current density of 100 mA g−1 is still achieved.
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Transition‐Metal (Fe, Co, Ni) Based Metal‐Organic Frameworks for Electrochemical Energy Storage
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Metadata
- Authors
- Liu, J., Wu, C., Xiao, D., Kopold, P., Gu, L., van Aken, P. A., Maier, J., & Yu, Y.
- Venue
- Small
- Publisher
- Wiley
- Published
- 2016-03-03
- Volume
- 12
- Issue
- 17
- Pages
- 2354-2364
- ISSN
- 1613-6810 (ISSN-L)
- 1613-6829
- OpenAlex
- W2290567516
- Cited by
- 331
- References
- 27
- FWCI
- 29.58
- Type
- journal article
- Language
- en
- Open access
- closed
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