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Recent Progress of Layered Transition Metal Oxide Cathodes for Sodium‐Ion Batteries
Abstract
Sodium‐ion batteries (SIBs) are attracting increasing attention and considered to be a low‐cost complement or an alternative to lithium‐ion batteries (LIBs), especially for large‐scale energy storage. Their application, however, is limited because of the lack of suitable host materials to reversibly intercalate Na+ ions. Layered transition metal oxides (NaxMO 2, M = Fe, Mn, Ni, Co, Cr, Ti, V, and their combinations) appear to be promising cathode candidates for SIBs due to their simple structure, ease of synthesis, high operating potential, and feasibility for commercial production. In the present work, the structural evolution, electrochemical performance, and recent progress of NaxMO 2 as cathode materials for SIBs are reviewed and summarized. Moreover, the existing drawbacks are discussed and several strategies are proposed to help alleviate these issues. In addition, the exploration of full cells based on NaxMO 2 cathodes and future perspectives are discussed to provide guidance for the future commercialization of such systems.
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Cites
Armand, M., & Tarascon, J.-M. (2008) · Nature · doi:10.1038/451652a · Cited by 19,612
Cradle-to-Gate Emissions from a Commercial Electric Vehicle Li-Ion Battery: A Comparative Analysis
Kim, H. C., Wallington, T. J., Arsenault, R., Bae, C., Ahn, S., & Lee, J. (2016) · Environmental Science & Technology · doi:10.1021/acs.est.6b00830 · Cited by 312
Cited by
Nanomaterials: a review of synthesis methods, properties, recent progress, and challenges
Baig, N., Kammakakam, I., & Falath, W. (2021) · Materials Advances · doi:10.1039/d0ma00807a · Cited by 3,262
Na‐Ion Batteries—Approaching Old and New Challenges
Goikolea, E., Palomares, V., Wang, S., de Larramendi, I. R., Guo, X., Wang, G., & Rojo, T. (2020) · Advanced Energy Materials · doi:10.1002/aenm.202002055 · Cited by 573
Self-citationLiquid metal batteries for future energy storage
Zhang, S., Liu, Y., Fan, Q., Zhang, C., Zhou, T., Kalantar-Zadeh, K., & Guo, Z. (2021) · Energy & Environmental Science · doi:10.1039/d1ee00531f · Cited by 268
Metadata
- Authors
- Liu, Q., Hu, Z., Chen, M., Zou, C., Jin, H., Wang, S., Chou, S., & Dou, S.
- Venue
- Small
- Publisher
- Wiley
- Published
- 2019-02-18
- Volume
- 15
- Issue
- 32
- Pages
- e1805381-e1805381
- ISSN
- 1613-6810 (ISSN-L)
- 1613-6829
- OpenAlex
- W2916590291
- Cited by
- 447
- References
- 2
- FWCI
- 19.65
- Type
- journal article
- Language
- en
- Open access
- closed
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- Liu, Q., Hu, Z., Chen, M., Zou, C., Jin, H., Wang, S., Chou, S., & Dou, S. (2019). Recent Progress of Layered Transition Metal Oxide Cathodes for Sodium‐Ion Batteries. Small. https://doi.org/10.1002/smll.201805381
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