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Enhancing Oxygen Evolution Reaction through Modulating Electronic Structure of Trimetallic Electrocatalysts Derived from Metal–Organic Frameworks

Li, Yuwen, Zhao, Tao, Lu, Mengting, Wu, Yuhang, Xie, Yuanbo, Xu, Hui, Gao, Junkuo, Yao, Juming, Qian, Guodong, Zhang, Qichun·2019·Small

Abstract

The construction of efficient, durable, and non‐noble metal electrocatalysts for oxygen evolution reaction (OER) is of great value but challenging. Herein, a facile method is developed to synthesize a series of trimetallic (W/Co/Fe) metal–organic frameworks (MOFs)‐derived carbon nanoflakes (CNF) with various Fe content, and an Fe‐dependent volcano‐type plot can be drawn out for WCoFex ‐CNF. The optimized WCoFe 0.3‐CNF (when the feed ratio of Fe/Co is 0.3) demonstrates superior electrocatalytic performance with a low overpotential of only 254 mV@10 mA cm−2 and excellent durability of 100 h. Further researches show that appropriate amount of iron doping can regulate the electronic structure, resulting in a favorable synergistic environment. This method may stimulate the exploration of electrocatalysts by utilizing MOFs as precursors while realizing electronic modulation by multimetal doping.

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Metadata

Authors
Li, Y., Zhao, T., Lu, M., Wu, Y., Xie, Y., Xu, H., Gao, J., Yao, J., Qian, G., & Zhang, Q.
Venue
Small
Publisher
Wiley
Published
2019-09-05
Volume
15
Issue
43
Pages
e1901940-e1901940
ISSN
  • 1613-6810 (ISSN-L)
  • 1613-6829
OpenAlex
W2972203065
Cited by
191
References
4
FWCI
7.73
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Enhancing Oxygen Evolution Reaction through Modulating Electronic Structure of Trimetallic Electrocatalysts Derived from Metal–Organic Frameworks. https://app.cochat.ai/papers/10.1002/smll.201901940
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Li, Y., Zhao, T., Lu, M., Wu, Y., Xie, Y., Xu, H., Gao, J., Yao, J., Qian, G., & Zhang, Q. (2019). Enhancing Oxygen Evolution Reaction through Modulating Electronic Structure of Trimetallic Electrocatalysts Derived from Metal–Organic Frameworks. Small. https://doi.org/10.1002/smll.201901940

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