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Cited by 150Electrocatalysts for Energy ConversionCO2 Reduction Techniques and CatalystsFuel Cells and Related Materials

Design and Synthesis of Noble Metal‐Based Alloy Electrocatalysts and Their Application in Hydrogen Evolution Reaction

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Cui, Zhibo, Jiao, Wensheng, Huang, ZeYi, Chen, Guanzhen, Zhang, Biao, Han, Yunhu, Huang, Wei·2023·Small
DOI 10.1002/smll.202301465
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Abstract

Hydrogen energy is regarded as the ultimate energy source for future human society, and the preparation of hydrogen from water electrolysis is recognized as the most ideal way. One of the key factors to achieve large‐scale hydrogen production by water splitting is the availability of highly active and stable electrocatalysts. Although non‐precious metal electrocatalysts have made great strides in recent years, the best hydrogen evolution reaction (HER) electrocatalysts are still based on noble metals. Therefore, it is particularly important to improve the overall activity of the electrocatalysts while reducing the noble metals load. Alloying strategies can shoulder the burden of optimizing electrocatalysts cost and improving electrocatalysts performance. With this in mind, recent work on the application of noble metal‐based alloy electrocatalysts in the field of hydrogen production from water electrolysis is summarized. In this review, first, the mechanism of HER is described; then, the current development of synthesis methods for alloy electrocatalysts is presented; finally, an example analysis of practical application studies on alloy electrocatalysts in hydrogen production is presented. In addition, at the end of this review, the prospects, opportunities, and challenges facing noble metal‐based alloy electrocatalysts are tried to discuss.

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  • The limited natural abundance and prohibitive costs of noble metal-based materials severely restrict their widespread commercialization.

    “Although extensive research has shown that noble metal-based materials generally exhibit the highest HER activity, their limited natural abundance and prohibitive costs severely restrict their widespread commercialization [9–13].”

    From Rational synthesis of Au3Cu@Rhx core–shell aerogel electrocatalysts for efficient hydrogen evolution reaction (2026) · cites this paper as [11]

    The Introduction states that the high cost of platinum-group metals limits their large-scale commercialization and wide application. It does not identify limited natural abundance as a cause of that restriction; it names low utilization and lack of durability instead. The supplied copy gives no page number for this passage. (LLM, conf=0.85)

    Experimental — accuracy not yet measured

  • Noble metal-based materials generally exhibit the highest HER activity.

    “Although extensive research has shown that noble metal-based materials generally exhibit the highest HER activity, their limited natural abundance and prohibitive costs severely restrict their widespread commercialization [9–13].”

    From Rational synthesis of Au3Cu@Rhx core–shell aerogel electrocatalysts for efficient hydrogen evolution reaction (2026) · cites this paper as [11]

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Cited by

Sorted by citations

Authors
Cui, Z., Jiao, W., Huang, Z., Chen, G., Zhang, B., Han, Y., & Huang, W.
Affiliations
Northwestern Polytechnical University (CN)
Corresponding author
Han, Yunhu
ORCID
Venue
Small
Publisher
Wiley
Published
2023-04-26
Volume
19
Issue
35
Pages
e2301465-e2301465
ISSN
  • 1613-6810 (ISSN-L)
  • 1613-6829
DOI
10.1002/smll.202301465
OpenAlex
W4367051105
Cited by
150
References
6
Citations by year
2026: 39 · 2025: 52 · 2024: 44 · 2023: 15
FWCI
2.30
Type
journal article
Language
en
Open access
Licence
onlinelibrary.wiley.com/termsAndConditions#vor (vor)
Locations
  • Small (publishedVersion)
  • PubMed (publishedVersion)
Funders
  • National Natural Science Foundation of China (22102132)
  • Natural Science Foundation of Ningbo (2021J053)
Topics
  • Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
  • Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
  • Physical Sciences › Engineering › Electrical and Electronic Engineering › Fuel Cells and Related Materials
Keywords
hydrogen evolution reaction, water electrolysis, hydrogen production, HER mechanism, electrocatalyst synthesis, noble metal loading reduction, electrocatalyst stability

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