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5‐Hydroxymethylfurfural (HMF). A Review Focussing on its Manufacture
Open accessAbstract
The acid‐catalysed dehydration of hexoses results in the formation of 5‐hydroxymethylfurfural (HMF). Fructose and inulin are especially good starting materials. A review is given of the many methods to produce HMF. The reaction kinetics are dealt with in the sections: raw material, hydrolysis and reversion, catalysts, reaction temperature and time, the concentration and the risk of polymerization and the solvent and HMF stability. Manufacturing processes are illustrated for fructose as the starting material: aqueous systems with homogeneous acid catalysis or those using ion‐exchangers as catalyst, systems using dimethyl sulfoxide as the solvent and those using other organic solvents. A short treatment is given on processes starting with glucose, work up procedures and the formation of levulinic acid and other in situ‐formed HMF‐derivatives.
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Cited by
Chemical Routes for the Transformation of Biomass into Chemicals
Corma, A., Iborra, S., & Velty, A. (2007) · Chemical Reviews · doi:10.1021/cr050989d · Cited by 5,970
Hydroxymethylfurfural, A Versatile Platform Chemical Made from Renewable Resources
van Putten, R.-J., van der Waal, J. C., de Jong, E., Rasrendra, C. B., Heeres, H. J., & de Vries, J. G. (2013) · Chemical Reviews · doi:10.1021/cr300182k · Cited by 2,886
Funke, A., & Ziegler, F. (2010) · Biofuels Bioproducts and Biorefining · doi:10.1002/bbb.198 · Cited by 2,001
Metal Chlorides in Ionic Liquid Solvents Convert Sugars to 5-Hydroxymethylfurfural
Zhao, H., Holladay, J. E., Brown, H., & Zhang, Z. C. (2007) · Science · doi:10.1126/science.1141199 · Cited by 1,997
Libra, J. A., Ro, K. S., Kammann, C., Funke, A., Berge, N. D., Neubauer, Y., Titirici, M.-M., Fühner, C., Bens, O., Kern, J., et al. (2011) · Biofuels · doi:10.4155/bfs.10.81 · Cited by 1,756
Metadata
- Authors
- Kuster, B. F. M.
- Venue
- Starch - Stärke
- Publisher
- Wiley
- Published
- 1990-01
- Volume
- 42
- Issue
- 8
- Pages
- 314-321
- ISSN
- 0038-9056 (ISSN-L)
- 1521-379X
- OpenAlex
- W2039365367
- Cited by
- 684
- References
- 0
- FWCI
- 3.25
- Type
- journal article
- Language
- en
- Open access
- green
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- Kuster, B. F. M. (1990). 5‐Hydroxymethylfurfural (HMF). A Review Focussing on its Manufacture. Starch - Stärke. https://doi.org/10.1002/star.19900420808
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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