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Cited by 323

The DOI matches its Crossref record; 11 of the 11 references it cites were found in a registry or an index.

Perchlorate: Problems, Detection, and Solutions

Motzer, William·2001·Environmental Forensics

Abstract

The perchlorate anion (ClO 4 m ) is produced when the solid salts of ammonium, potassium, and sodium perchlorate, and perchloric acid dissolve in water. Ammonium perchlorate, used in solid rocket engine fuels, has a limited shelf life and must periodically be replaced. Before 1997, perchlorate could not be readily detected in groundwater at concentrations below 100 µg/L, until the California Department of Health Services developed an acceptable analytical method that lowered the detection limit to 4 µg/L. Subsequently, groundwater containing perchlorate were soon encountered in several western states, and contamination became apparent in Colorado River water. Most perchlorate salts have high water solubilities; concentrated solutions have densities greater than water. Once dissolved, perchlorate is extremely mobile, requiring decades to degrade. Health effects from ingesting low dosage perchlorate-contaminated water are not well known: it interferes with the body's iodine intake, causing an inhibition of human thyroid production. Contaminated surface and groundwater treatment may require bio- and/or phytoremediation technologies. Perchlorate in groundwater is relatively unretarded; it probably travels by advection. Therefore, it may be used as a tracer for hydrocarbon and metal contaminants that are significantly more retarded. Possible forensic techniques include chlorine isotopes for defining multiple or commingled perchlorate plumes.

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Metadata

Authors
Motzer, W.
Venue
Environmental Forensics
Published
2001-01-01
Volume
2
Issue
4
Pages
301-311
ISSN
1527-5922 (ISSN-L)
OpenAlex
W2036890940
Cited by
323
References
11
FWCI
7.48
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Perchlorate: Problems, Detection, and Solutions. https://app.cochat.ai/papers/10.1006/enfo.2001.0059
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Motzer, W. (2001). Perchlorate: Problems, Detection, and Solutions. Environmental Forensics. https://doi.org/10.1006/enfo.2001.0059

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