Nanodroplet Formations in Electrospun Fibers of Immiscible Polymer Blends and Their Effects on Fractionated Crystallization
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As-spun polymer blend fibers usually display co-continuous morphology and break into nanodroplets through thermal annealing above the Tg of the matrix due to Plateau-Rayleigh instability.
“As-spun polymer blend fibers usually display co-continuous morphology and break into nanodroplets through thermal annealing at temperatures above the T g of the matrix due to Plateau-Rayleigh instability.”
From Fractionated crystallization in semicrystalline polymers (2021) · cites this paper as [62]
In electrospun PEO/PS (30/70) blend fibers, when annealing temperature is below 95°C, the majority crystallizes heterogeneously at around 40°C; when annealing temperature is above 125°C, fibers break into numerous nanodroplets and homogeneous/surface-induced nucleation at large undercooling dominates due to lack of heterogeneities.
“When the annealing temperature is below 95 °C, the temperature is not enough to break the largest part of the electrospun fibers, therefore, the majority of PEO/PS blend will crystallize heterogeneously at around 40 °C ( Fig. 10 A).However, when the annealing temperature is above 125 °C, PEO/PS blend fibers break into numerous nanodroplets and homogeneous/surface-induced nucleation at large under”
From Fractionated crystallization in semicrystalline polymers (2021) · cites this paper as [62]
Cites
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Crystallization Within Block Copolymer Mesophases
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“Finely dispersed immiscible polymer blends [1], polymers in nanopores [14, 15], and microphase-separated crystalline block copolymers [16] have been used to achieve confined polymer crystallization with uniform crystal orientation.”
MethodSome novel crystallization kinetic peculiarities in finely dispersing polymer blends
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Fractionated crystallization of α-and β-nucleated polypropylene droplets
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Fractionated crystallization in semicrystalline polymers
Sangroniz, L., Wang, B., Su, Y., Liu, G., Cavallo, D., Wang, D., & Müller, A. J. (2021) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2021.101376 · Cited by 102 · see citing works
- Authors
- Zhong, G., Zhu, L., & Fong, H.
- Affiliations
- Case Western Reserve University (US)
- South Dakota School of Mines and Technology (US)
- Venue
- Lecture Notes in Nanoscale Science and Technology
- Publisher
- Springer New York
- Published
- 2013
- Pages
- 25-50
- ISSN
- 2195-2159 (ISSN-L)
- 2195-2167
- OpenAlex
- W135754514
- Cited by
- 4
- References
- 10
- Citations by year
- 2023: 1 · 2021: 1 · 2020: 1 · 2019: 1
- FWCI
- 0.00
- Type
- book chapter
- Language
- en
- Open access
- closed
- Licence
- Locations
- Lecture notes in nanoscale science and technology (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Physical Sciences › Materials Science › Materials Chemistry › Block Copolymer Self-Assembly
- Physical Sciences › Earth and Planetary Sciences › Atmospheric Science › nanoparticles nucleation surface interactions
- Keywords
- electrospun nanofibers, immiscible polymer blends, fractional crystallization, homogeneous nucleation, Rayleigh-Plateau instability, annealing, semicrystalline polymers, polyvinylidene fluoride, poly(ethylene oxide), polyethylene, polypropylene, nanoconfinement, crystal morphology
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