Confined crystallization phenomena in immiscible polymer blends with dispersed micro-and nanometer sized PA6 droplets, part 3: crystallization kinetics and crystallinity of micro-and nanometer sized PA6 droplets crystallizing at high supercoolings
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In PA6 blends, the first-order kinetics has been associated with homogeneous nucleation.
“In the case of PA6 blends [ 34 , 35 ], the firstorder kinetics has been associated with the occurrence of homogeneous nucleation.”
From Fractionated crystallization in semicrystalline polymers (2021) · cites this paper as [34]
Equation 6 has been applied to describe crystallization kinetics of several immiscible blends with droplet morphology, namely PS/PA6, compatibilized ethylene/1-octene copolymer/PA6, and neat and nucleated PS/iPP blends.
“In the literature, Equation 6has been applied to describe the crystallization kinetics of several immiscible blends with droplet morphology, namely PS/PA6 [34] , compatibilized ethylene/1-octene copolymer/PA6 [35] , and more recently neat and nucleated PS/iPP blends [7] .”
From Fractionated crystallization in semicrystalline polymers (2021) · cites this paper as [34]
Tol et al. found the fractionated crystallization temperature of the compatibilized PS matrix systematically above that of PPE/PS/SMA over the entire droplet size range; the difference was attributed to surface nucleation, although vitrification of the matrix could also play a role.
“The fractionated crystallization temperature of the compatibilized PS matrix was systematically above that of the PPE/PS/SMA in the entire range of droplet size.Given the similar interfacial tension and identical morphology, the difference was attributed to surface nucleation, although vitrification of the matrix could also play a role in inducing crystallization.”
From Fractionated crystallization in semicrystalline polymers (2021) · cites this paper as [34]
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Agwuncha, S. C., Owonubi, S. J., Sadiku, E. R., Varaprasad, K., Ray, S. S., Selvam, S. P., Shittu, T. A., Shanavas, A., & Mukwevho, E. (2015) · Elsevier eBooks · doi:10.1016/b978-0-323-39408-6.00013-3 · Cited by 3 · see citing works
Molecular structure and driving force to metastable states: Janus faces in polymer crystallization
Mathot, V. (2018) · Polymer International · doi:10.1002/pi.5671 · Cited by 2 · see citing works
Tol, R. T., Mathot, V., Reynaers, H., & Groeninckx, G. (2005) · CRC Press eBooks · doi:10.1201/9781420026542-12 · Cited by 2 · see citing works
Crystallization behavior of polyamide 6 confined in a strip-like rubbery phase
Shi, H., Shi, D., Luan, S., Jiang, T., Yin, J., Li, R. K. Y., & Jiang, S. (2013) · RSC Advances · doi:10.1039/c3ra45141k · Cited by 1 · see citing works
Tol, R., Mathot, V., Reynaers, H., & Groeninckx, G. (2005) · CRC Press eBooks · doi:10.1201/9781420026542.ch12 · Cited by 1 · see citing works
Codou, A., Mohanty, A. K., & Misra, M. (2019) · AIP conference proceedings · doi:10.1063/1.5121670
- Authors
- Tol, R. T., Mathot, V. B. F., & Groeninckx, G.
- Affiliations
- UCLouvain (BE)
- Corresponding author
- Groeninckx, G.
- ORCID
- Mathot, V.B.F.
- Venue
- Polymer
- Publisher
- Elsevier BV
- Published
- 2005-04
- Volume
- 46
- Issue
- 9
- Pages
- 2955-2965
- ISSN
- 0032-3861 (ISSN-L)
- OpenAlex
- W2093974764
- Cited by
- 78
- References
- 50
- Citations by year
- 2026: 1 · 2023: 2 · 2022: 7 · 2021: 5 · 2020: 3 · 2019: 5 · 2018: 3 · 2017: 3 · 2016: 2 · 2015: 2 · 2014: 6 · 2013: 11 · 2012: 3
- FWCI
- 4.39
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Polymer (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Physical Sciences › Materials Science › Materials Chemistry › Crystallization and Solubility Studies
- Physical Sciences › Materials Science › Materials Chemistry › Solidification and crystal growth phenomena
- Keywords
- confined crystallization, immiscible polymer blends, compatibilized blends, styrene-maleic anhydride copolymer, crystallization kinetics, crystallinity, fractional crystallization, random nucleation, heterogeneous nucleation, droplet size effects, crystal reorganization
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