The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Light-Induced Spin Crossover and the High-Spin→Low-Spin Relaxation
Open accessAbstract
The discovery of a light-induced spin transition at cryogenic temperatures in a series of iron(II) spin-crossover compounds in 1984 has had an enormous impact on spin-crossover research. Apart from being an interesting photophysical phenomenon in its own right, it provided the means of studying the dynamics of the intersystem crossing process between the high-spin and the low-spin state in a series of compounds and over a large temperature range. It could thus be firmly established that intersystem crossing in spin-crossover compounds is a tunnelling process, with a limiting low-temperature lifetime below 50 K and a thermally activated region above 100 K. This review begins with an elucidation of the mechanism of the light-induced spin transition, followed by an in depth discussion of the chemical and physical factors, including cooperative effects, governing the lifetimes of the light-induced metastable states.
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Citations
Cites
Photophysics of aromatic molecules
Birks, J. B. (1970) · Cited by 3,326
Thermal and Optical Switching of Iron( II ) Complexes
Gütlich, P., Hauser, A., & Spiering, H. (1994) · Angewandte Chemie International Edition in English · doi:10.1002/anie.199420241 · Cited by 2,146
Self-citationCooperative phenomena and light-induced bistability in iron(II) spin-crossover compounds
Hauser, A., Jeftić, J., Romstedt, H., Hinek, R., & Spiering, H. (1999) · Coordination Chemistry Reviews · doi:10.1016/s0010-8545(99)00111-3 · Cited by 310
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Cited by
Molecular spin crossover phenomenon: recent achievements and prospects
Bousseksou, A., Molnár, G., Salmon, L., & Nicolazzi, W. (2011) · Chemical Society Reviews · doi:10.1039/c1cs15042a · Cited by 1,379
Janet, J. P., Chan, L., & Kulik, H. J. (2018) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.8b00170 · Cited by 200
Strategies and Software for Machine Learning Accelerated Discovery in Transition Metal Chemistry
Nandy, A., Duan, C., Janet, J. P., Gugler, S., & Kulik, H. J. (2018) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.8b04015 · Cited by 161
A Simple Approach for Predicting the Spin State of Homoleptic Fe(II) Tris-diimine Complexes
Phan, H., Hrudka, J. J., Igimbayeva, D., Lawson Daku, L. M., & Shatruk, M. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b02098 · Cited by 111
Seeing Is Believing: Experimental Spin States from Machine Learning Model Structure Predictions
Taylor, M. G., Yang, T., Lin, S., Nandy, A., Janet, J. P., Duan, C., & Kulik, H. J. (2020) · The Journal of Physical Chemistry A · doi:10.1021/acs.jpca.0c01458 · Cited by 81
Metadata
- Authors
- Hauser, A.
- Venue
- Topics in Current Chemistry
- Publisher
- Springer Berlin Heidelberg
- Published
- 2012-02-24
- Pages
- 155-198
- ISSN
- 0340-1022 (ISSN-L)
- 1436-5049
- OpenAlex
- W2470683402
- Cited by
- 528
- References
- 3
- FWCI
- 750.82
- Type
- book chapter
- Language
- en
- Open access
- green
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