Cited by 111Magnetism in coordination complexesMetal-Catalyzed Oxygenation MechanismsInorganic and Organometallic Chemistry

A Simple Approach for Predicting the Spin State of Homoleptic Fe(II) Tris-diimine Complexes

Open access
Phan, Hoa, Hrudka, Jeremy J., Igimbayeva, Dilyara, Lawson Daku, Latévi M., Shatruk, Michael·2017·Journal of the American Chemical Society

Abstract

ion with chelating diimine ligands. The approach is based on the analysis of a single metric parameter within a free (noncoordinated) ligand: the interatomic separation between the N-donor metal-binding sites. An extensive analysis of existing complexes allows the determination of critical N···N distances that dictate the regions of stability for the high-spin and low-spin complexes, as well as the intermediate range in which the magnetic bistability (spin crossover) can be observed. The prediction has been tested on several complexes that demonstrate the validity of our method.

Integrity signals

Registry

Crossref · 10.1021/jacs.7b02098

Cites

96 of 96 references verified0 citation errors · 0 not checkable

Statistics

Recomputing p-values needs the paper’s full text.

Claims the paper makes

We couldn’t retrieve this paper’s full text, so its claims and self-check weren’t run. The registry and citation checks still apply.

Claims other papers make about this one

Each is checked against this paper’s own text: does it say what the citing paper says it does?

  • The likelihood of a TMC to exhibit spin-crossover behavior has been predicted based on the ligand nitrogen-nitrogen separation, and similar features have been invoked for predicting single-molecule magnet behavior.

    “The likelihood of a TMC to exhibit spin-crossover behavior has been predicted based on the ligand nitrogen-nitrogen separation (83), and similar features have been invoked for predicting single-molecule magnet behavior (84).”

Cites

Flagged first, then by citations

Cited by

Sorted by citations

Authors
Phan, H., Hrudka, J. J., Igimbayeva, D., Lawson Daku, L. M., & Shatruk, M.
Affiliations
  • Florida State University (US)
  • L. N. Gumilyov Eurasian National University (KZ)
  • Department of Physical Chemistry, University of Geneva, 30 Quai Ernest-Ansermet, CH-1211 Geneva 4, Switzerland
Corresponding author
Shatruk, Michael
Venue
Journal of the American Chemical Society
Published
2017-04-27
Volume
139
Issue
18
Pages
6437-6447
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2606898172
Cited by
111
References
96
Citations by year
2026: 5 · 2025: 8 · 2024: 10 · 2023: 5 · 2022: 9 · 2021: 13 · 2020: 21 · 2019: 8 · 2018: 26 · 2017: 6
FWCI
5.68
Type
journal article
Language
en
Open access
Licence
cc-by
Locations
  • Journal of the American Chemical Society (publishedVersion)
  • PubMed (publishedVersion)
  • Archive ouverte UNIGE (University of Geneva) (submittedVersion, cc-by)
Funders
Division of Chemistry (CHE-1464955)
Topics
  • Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Magnetism in coordination complexes
  • Physical Sciences › Chemistry › Inorganic Chemistry › Metal-Catalyzed Oxygenation Mechanisms
  • Physical Sciences › Chemistry › Organic Chemistry › Inorganic and Organometallic Chemistry
Keywords
iron(II) complexes, homoleptic complexes, spin crossover, magnetic bistability, diimine ligands, coordination chemistry

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review