The DOI matches its Crossref record; 22 of the 22 references it cites were found in a registry or an index.
Effects of aromatic ring type on reactions subsequent to the β-O-4 bond cleavage of non-phenolic lignin model compounds under alkaline pulping conditions
Open accessAbstract
The reaction products of an alkaline treatment of non-phenolic β-O-4-type lignin model compounds (C₆–C₂-type) consisting of p-hydroxyphenyl (H), guaiacyl (G), and/or syringyl (S) nuclei were identified and quantified. This was performed to examine how the type of H, G, or S nucleus affect the reaction product profiles. The major identified and quantified reaction products were phenol derivatives that were liberated from the aryl sides of the β-O-4 ether bonds of the lignin model compounds. Other products included derivatives of phenylethane-1,2-diol (glycol-type), benzaldehyde, and acetophenone, which originated from the alkyl sides of the β-O-4 ether bonds of the lignin model compounds. Although the type of aromatic nucleus of the aryl side of the β-O-4 ether bond of the lignin model compounds did not significantly affect the profile of the reaction products, the type of the alkyl side nucleus was influential. The glycol-type compound was the exclusive major reaction product when the S nucleus was on the alkyl side of the β-O-4 ether bond. On the other hand, when the H or G nucleus was present, a benzaldehyde derivative was the other major reaction product.
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“Results show that lignin fractions with different molecular weight distributions, linkages type, functional groups content, and S/G ratio can be obtained, where lignin with more methoxy contains the stronger cracking of β aryl ether bonds [191].”
From A review on lignin pyrolysis: pyrolytic behavior, mechanism, and relevant upgrading for improving process efficiency (2022) · cites this paper as [191]
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“Thermal stability is directly related to lignin structure (e.g., the content of methoxy [191]), which indicates that the higher dispersity, the lower yield of char residue, suggesting the worse thermal stability [214].”
From A review on lignin pyrolysis: pyrolytic behavior, mechanism, and relevant upgrading for improving process efficiency (2022) · cites this paper as [191]
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Cited by
Lu, X., & Gu, X. (2022) · Biotechnology for Biofuels and Bioproducts · doi:10.1186/s13068-022-02203-0 · Cited by 354
“Results show that lignin fractions with different molecular weight distributions, linkages type, functional groups content, and S/G ratio can be obtained, where lignin with more methoxy contains the stronger cracking of β aryl ether bonds [191].”
BackgroundLu, M., Sun, S., Li, X., Liu, Q., Zhang, W., & Qiu, X. (2024) · International Journal of Biological Macromolecules · doi:10.1016/j.ijbiomac.2024.138331 · Cited by 41
Pyrolysis characteristics and volatiles formation rule of organic solvent fractionized kraft lignin
Chen, S., Cheng, H., & Wu, S. (2020) · Fuel · doi:10.1016/j.fuel.2020.117520 · Cited by 40
Hirano, Y., Izawa, A., Hosoya, T., & Miyafuji, H. (2022) · Reaction Chemistry & Engineering · doi:10.1039/d2re00036a · Cited by 24
Hosoya, T., Kawase, K., Hirano, Y., Ikeuchi, M., & Miyafuji, H. (2021) · Journal of Wood Chemistry and Technology · doi:10.1080/02773813.2021.1998127 · Cited by 17
Metadata
- Authors
- Shimizu, S., Posoknistakul, P., Akiyama, T., Yokoyama, T., & Matsumoto, Y.
- Affiliations
- The University of Tokyo (JP)
- Corresponding author
- Yokoyama, Tomoya
- Venue
- Journal of Wood Science
- Published
- 2018-06-20
- Volume
- 64
- Issue
- 5
- Pages
- 664-674
- ISSN
- 1435-0211 (ISSN-L)
- 1611-4663
- OpenAlex
- W2808861011
- Cited by
- 14
- References
- 22
- Citations by year
- 2026: 1 · 2025: 3 · 2024: 1 · 2023: 1 · 2022: 3 · 2021: 1 · 2020: 2 · 2019: 2
- FWCI
- 0.50
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Licence
- www.springer.com/tdm (tdm)
- www.springer.com/tdm (vor)
- Locations
- Journal of Wood Science (publishedVersion)
- Funders
- Japan Society for the Promotion of Science (Grant-in-Aid for JSPS Fellows (DC2), No. 26-11150)
- Topics
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Lignin and Wood Chemistry
- Physical Sciences › Engineering › Building and Construction › Wood Treatment and Properties
- Life Sciences › Biochemistry, Genetics and Molecular Biology › Molecular Biology › Plant-derived Lignans Synthesis and Bioactivity
- Keywords
- β-O-4 bond cleavage, alkaline pulping, reaction products, phenol derivatives, benzaldehyde, acetophenone, lignin degradation
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- Shimizu, S., Posoknistakul, P., Akiyama, T., Yokoyama, T., & Matsumoto, Y. (2018). Effects of aromatic ring type on reactions subsequent to the β-O-4 bond cleavage of non-phenolic lignin model compounds under alkaline pulping conditions. Journal of Wood Science. https://doi.org/10.1007/s10086-018-1739-3
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