Application of shape memory polyurethane in orthodontic
Abstract
A shape memory polymer wire for orthodontic application was prepared by melt-spinning of polyurethane block copolymer (PU) which was synthesized in a two-step process from a reaction of 4,4'-methylene bis(phenylisocyanate), poly(ε-caprolactone)diol (PCL), and 1,4-butanediol. An orthodontic test using the PU wire was carried out in an orthodontic model with a metal bracket. High shape recovery force of 70 gf for PU wire at 40 wt% hard segment content could be preserved for even 1 month after a shape recovery force test at a constant temperature of 50°C. The shape recovery force decreased exponentially during the initial 2 h, but reached an equilibrium shape recovery force of 50 gf after about 20 days. It was found that this shape recovery force was sufficient to correct misaligned teeth in the orthodontic test. The shape memory PU wire possesses strong potential as a novel orthodontic appliance with esthetically appealing appearance.
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In a dental arch model, only a much too fast shape recovery has been realized that would not allow proper remodeling of bone around the roots of the teeth.
“However, in a dental arch model, so far only a much too fast shape recovery has been realized that would not allow proper remodeling of bone around the roots of the teeth.”
From Shape-memory polymers as a technology platform for biomedical applications (2010) · cites this paper as [122]
In a thermoplastic SMP containing PCL building blocks, maintenance of the wire's recovery forces over months was observed at least in a water-free environment.
“In the present example with a thermoplastic SMP containing PCL building blocks, a maintenance of the wire's recovery forces over months was observed at least in a water-free environment.”
From Shape-memory polymers as a technology platform for biomedical applications (2010) · cites this paper as [122]
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An Overview of 3D-Printed Smart Polymers and Composites
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- Authors
- Jung, Y. C., & Cho, J. W.
- Affiliations
- Konkuk University (KR)
- Corresponding author
- Cho, Jae Whan
- Venue
- Journal of Materials Science: Materials in Medicine
- Published
- 2008-07-24
- Volume
- 21
- Issue
- 10
- Pages
- 2881-2886
- ISSN
- 0957-4530 (ISSN-L)
- 1573-4838
- OpenAlex
- W1967759754
- Cited by
- 106
- References
- 19
- Citations by year
- 2026: 4 · 2025: 6 · 2024: 6 · 2023: 10 · 2022: 12 · 2021: 9 · 2020: 9 · 2019: 10 · 2018: 9 · 2017: 5 · 2016: 3 · 2015: 6 · 2014: 5 · 2013: 4 · 2012: 4
- FWCI
- 1.15
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- www.springer.com/tdm (tdm)
- Locations
- Journal of Materials Science Materials in Medicine (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
- Physical Sciences › Engineering › Mechanical Engineering › Advanced Materials and Mechanics
- Health Sciences › Dentistry › Orthodontics › Orthodontics and Dentofacial Orthopedics
- Keywords
- shape memory polyurethane, orthodontic appliances, polyurethane block copolymers, polycaprolactone, 1,4-butanediol, melt spinning, hard segment content, metal brackets
- MeSH terms
- Dental Materials, Humans, Malocclusion, Materials Testing, Orthodontic Wires, Polyurethanes, Stress, Mechanical, Orthodontic Appliance Design, Spectroscopy, Fourier Transform Infrared, In Vitro Techniques
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