Cited by 33Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesThermal and Kinetic Analysis

The DOI matches its Crossref record.

Role of thermal history on the thermal behavior of poly(L-lactic acid) studied by DSC and optical microscopy

Wang, Y., Mano, J. F.·2005·Journal of Thermal Analysis and Calorimetry

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Crossref · 10.1007/s10973-005-0631-8

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  • The high-temperature exothermic peak observed before the main melting peak in PLLA has been attributed to recrystallization or to the formation of a more stable crystalline phase.

    “The one at high temperatures has been previously observed for PLLA homopolymers of different molecular weights during heating scans and has been attributed to recrystallization 49 -51 or to the formation of a more stable crystalline phase; see below. 14,52 -57”
  • The higher the crystallization rates, the more likely small and imperfect crystals change successively into more stable crystals through a melt-recrystallization mechanism or by a phase transition, giving rise to the exothermic signal before the melting peak.

    “The higher the crystallization rates, the more likely it will be for small and imperfect crystals to change successively into more stable crystals through a melt-recrystallization mechanism or by a phase transition, giving rise to the exothermic signal before the melting peak. 49,50”
  • The appearance and intensity of the small exotherm observed before the main melting peak depend on cooling and heating rates.

    “Theappearance and intensity of the small exotherm observed before the main melting peak have been reported as being dependent on cooling and heating rates. 49,50”

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Metadata

Authors
Wang, Y., & Mano, J. F.
Affiliations
  • 3B's Research Group (PT)
  • University of Minho (PT)
Venue
Journal of Thermal Analysis and Calorimetry
Published
2005-03
Volume
80
Issue
1
Pages
171-175
ISSN
  • 1388-6150 (ISSN-L)
  • 1572-8943
OpenAlex
W2028999056
Cited by
33
References
0
Citations by year
2026: 2 · 2025: 2 · 2023: 1 · 2021: 1 · 2019: 1 · 2017: 2 · 2015: 2 · 2014: 3 · 2013: 5 · 2012: 2
FWCI
2.48
Type
journal article
Language
en
Open access
closed
Locations
Journal of Thermal Analysis and Calorimetry (publishedVersion)
Topics
  • Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
  • Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
  • Physical Sciences › Materials Science › Materials Chemistry › Thermal and Kinetic Analysis
Keywords
poly(L-lactic acid), thermal history, cold crystallization, melting behavior, amorphous polymers, metastable phases, melt recrystallization, heating rate effects, polymer crystallization

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