Oxidation of Binary FeCr Alloys (Fe–2.25Cr, Fe–10Cr, Fe–18Cr and Fe–25Cr) in O2 and in O2 + H2O Environment at 600 °C
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Regardless of the environments studied, the oxide scales formed after breakaway have been composed of an outward-growing almost pure Fe oxide and an inward-growing oxide with a more complex microstructure and varying composition.
“Regardless of the environments studied, the oxide scales have been composed of an outward-growing almost pure Fe oxide, and an inward-growing oxide with a more complex microstructure and varying composition.”
From The influence of Nickel on the corrosion protection of FeCrNi alloys after breakaway corrosion at 600 °C (2024) · cites this paper as [19]
Alloys with low Cr content (Fe2.25Cr, Fe5Cr3Al) and the 34 wt% Ni alloy (Fe18Cr34Ni) do not form a primary corrosion protection under the studied conditions, but an Fe-rich oxide scale similar to the oxide scale formed in the presence of K2CO3 (secondary regime).
“Note that the alloys with low Cr content (Fe2.25Cr[20], Fe5Cr3Al) and the 34 wt% Ni alloy (Fe18Cr34Ni) do not form a primary corrosion protection under the studied conditions, but an Fe-rich oxide scale, similar to the oxide scale formed in the presence of K 2 CO 3 (in the secondary corrosion regime).”
Most samples formed a slow-growing Cr/Al-rich oxide scale in the mild exposure environment (O2 + N2), with the exceptions being alloys with low Cr content (Fe2.25Cr, Fe5Cr3Al) and the alloy with 34 wt% Ni (Fe18Cr34Ni).
“This is in good agreement with the results from this study, showing that most of the samples formed a slow-growing Cr/Al-rich oxide scale in the mild exposure environment (O 2 + N 2 ) with the exception being the alloys with low Cr content (Fe2.25Cr[20], Fe5Cr3Al) and the alloy with 34 wt% Ni (Fe18Cr34Ni) (see Fig. 2 and 4).”
Cites
Paralinear Oxidation of Chromium in O2 + H2O Environment at 600–700 °C
Pujilaksono, B., Jonsson, T., Halvarsson, M., Panas, I., Svensson, J.-E., & Johansson, L.-G. (2008) · Oxidation of Metals · doi:10.1007/s11085-008-9114-1 · Cited by 59 · see citing works
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Jonsson, T., Karlsson, S., Hooshyar, H., Sattari, M., Liske, J., Svensson, J.-E., & Johansson, L.-G. (2016) · Oxidation of Metals · doi:10.1007/s11085-016-9610-7 · Cited by 103 · see citing works
Self-citationOxidation of Fe–10Cr in O2 and in O2+H2O environment at 600°C: A microstructural investigation
Jonsson, T., Pujilaksono, B., Heidari, H., Liu, F., Svensson, J.-E., Halvarsson, M., & Johansson, L.-G. (2013) · Corrosion Science · doi:10.1016/j.corsci.2013.06.016 · Cited by 64 · see citing works
Self-citationEklund, J., Jönsson, B., Persdotter, A., Liske, J., Svensson, J.-E., & Jonsson, T. (2018) · Corrosion Science · doi:10.1016/j.corsci.2018.09.004 · Cited by 55 · see citing works
Self-citationPersdotter, A., Eklund, J., Liske, J., & Jonsson, T. (2020) · Corrosion Science · doi:10.1016/j.corsci.2020.108961 · Cited by 44 · see citing works
Self-citationHigh-temperature oxidation of FeCr(Ni) alloys: the behaviour after breakaway
Jonsson, T., Larsson, H., Karlsson, S., Hooshyar, H., Sattari, M., Liske, J., Svensson, J.-E., & Johansson, L.-G. (2017) · Oxidation of Metals · doi:10.1007/s11085-017-9731-7 · Cited by 37 · see citing works
Self-citationZhou, R., Wang, F., Xu, K., Yuan, Y., Chen, L., Lou, M., Khvan, A. V., & Chang, K. (2023) · Materials Characterization · doi:10.1016/j.matchar.2023.113221 · Cited by 27 · see citing works
Ssenteza, V., Eklund, J., Hanif, I., Liske, J., & Jonsson, T. (2023) · Corrosion Science · doi:10.1016/j.corsci.2022.110896 · Cited by 25 · see citing works
Self-citationSsenteza, V., Eklund, J., Bigdeli, S., & Jonsson, T. (2024) · Corrosion Science · doi:10.1016/j.corsci.2023.111654 · Cited by 23 · see citing works
Self-citationEklund, J., Persdotter, A., Hanif, I., Bigdeli, S., & Jonsson, T. (2021) · Corrosion Science · doi:10.1016/j.corsci.2021.109584 · Cited by 23 · see citing works
Self-citationPersdotter, A., Larsson, H., Eklund, J., Bigdeli, S., & Jonsson, T. (2024) · Corrosion Science · doi:10.1016/j.corsci.2024.112473 · Cited by 1 · see citing works
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- Authors
- Pujilaksono, B., Jonsson, T., Heidari, H., Halvarsson, M., Svensson, J.-E., & Johansson, L.-G.
- Affiliations
- Chalmers University of Technology (SE)
- Corresponding author
- Jonsson, T.
- Venue
- Oxidation of Metals
- Published
- 2011-01-11
- Volume
- 75
- Issue
- 3-4
- Pages
- 183-207
- ISSN
- 0030-770X (ISSN-L)
- 1573-4889
- OpenAlex
- W2018456740
- Cited by
- 109
- References
- 1
- Citations by year
- 2026: 4 · 2025: 6 · 2024: 15 · 2023: 10 · 2022: 8 · 2021: 5 · 2020: 9 · 2019: 6 · 2018: 12 · 2017: 8 · 2016: 4 · 2015: 6 · 2014: 3 · 2013: 9 · 2012: 1
- FWCI
- 9.21
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- www.springer.com/tdm (tdm)
- Locations
- Oxidation of Metals (publishedVersion)
- Chalmers Publication Library (Chalmers University of Technology) (submittedVersion)
- Chalmers Research (Chalmers University of Technology) (submittedVersion)
- Funders
- Stiftelsen för Strategisk Forskning
- Kungliga Tekniska Högskolan
- Division of Materials Research
- Topics
- Physical Sciences › Engineering › Aerospace Engineering › High-Temperature Coating Behaviors
- Physical Sciences › Materials Science › Metals and Alloys › Hydrogen embrittlement and corrosion behaviors in metals
- Physical Sciences › Materials Science › Materials Chemistry › Nuclear Materials and Properties
- Keywords
- Fe-Cr alloys, high-temperature oxidation, protective oxide scale, magnetite, hematite, breakaway oxidation, incubation period, chromium content, oxide scale composition
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