Stabilization of non-standard conformations of the annulene rings in cyclobutadiene-framed [n]annulenes (n = 8, 10, 12, 14) and their beryllium sandwich-like complexes: a quantum chemical study
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It is very difficult to estimate the resonance stabilization in ten-electron delocalized π-systems such as [10]annulene derivatives, due to severe levels of strain in the carbon framework.
“it is very dif fi cult to estimate the resonance stabilization in tenelectron delocalized π -systems such as [10]annulene derivatives, due to the presence of severe levels of strain in the carbon framework 42 .”
From Double aromaticity arising from σ- and π-rings (2018) · cites this paper as [42]
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Double aromaticity arising from σ- and π-rings
Furukawa, S., Fujita, M., Kanatomi, Y., Minoura, M., Hatanaka, M., Morokuma, K., Ishimura, K., & Saito, M. (2018) · Communications Chemistry · doi:10.1038/s42004-018-0057-4 · Cited by 73 · see citing works
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Ponikvar‐Svet, M., Zeiger, D. N., & Liebman, J. F. (2017) · Structural Chemistry · doi:10.1007/s11224-017-0983-2 · Cited by 8 · see citing works
Gribanova, T. N., Minyaev, R. M., Minkin, V. I., & Boldyrev, A. I. (2018) · Physical Chemistry Chemical Physics · doi:10.1039/c8cp05444d · Cited by 3 · see citing works
Self-citationGribanova, T. N., Minyaev, R. M., & Minkin, V. I. (2024) · Mendeleev Communications · doi:10.1016/j.mencom.2024.10.010
Self-citation
- Authors
- Gribanova, T. N., Minyaev, R. M., & Minkin, V. I.
- Affiliations
- Southern Federal University (RU)
- Corresponding author
- Minyaev, Ruslan M.
- Venue
- Structural Chemistry
- Published
- 2016-04-13
- Volume
- 27
- Issue
- 4
- Pages
- 1229-1240
- ISSN
- 1040-0400 (ISSN-L)
- 1572-9001
- OpenAlex
- W2337177593
- Cited by
- 5
- References
- 65
- Citations by year
- 2024: 1 · 2018: 2 · 2017: 2
- FWCI
- 0.61
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- www.springer.com/tdm (tdm)
- Locations
- Structural Chemistry (publishedVersion)
- Funders
- financial support from the basic part of internal SFedU grant (project № 213.01-2014/005)
- Topics
- Physical Sciences › Chemistry › Organic Chemistry › Synthesis and Properties of Aromatic Compounds
- Physical Sciences › Chemistry › Inorganic Chemistry › Synthesis and characterization of novel inorganic/organometallic compounds
- Physical Sciences › Chemistry › Organic Chemistry › Supramolecular Chemistry and Complexes
- Keywords
- cyclobutadiene, π-complexation, polycyclic hydrocarbons
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