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Photoreduction of CO2 on BiOCl nanoplates with the assistance of photoinduced oxygen vacancies

Zhang, Ling, Wang, Wenzhong, Jiang, Dong, Gao, Erping, Sun, Songmei·2015·Nano Research

Abstract

CO 2 photoreduction by semiconductors is of growing interest. Fabrication of oxygen-deficient surfaces is an important strategy for enhancing CO 2 photoreduction activity. However, regeneration of the oxygen vacancies in photocatalysts is still a problem since an oxygen vacancy will be filled up by the O atom from CO 2 after the dissociation process. Herein, we have fabricated highly efficient BiOCl nanoplates with photoinduced oxygen vacancies. Oxygen vacancies were easily regenerated by light irradiation due to the high oxygen atom density and low Bi-O bond energy even when the oxygen vacancies had been filled up by the O atom in the photocatalytic reactions. These oxygen vacancies not only enhanced the trapping capability for CO 2 , but also enhanced the efficiency of separation of electron-hole pairs, which resulted in the photocatalytic CO 2 reduction under simulated solar light. Furthermore, the generation and recovery of the defects in the BiOCl could be realized during the photocatalytic reduction of CO 2 in water. The existence of photoinduced defects in thin BiOCl nanoplates undoubtedly leads to new possibilities for the design of solar-driven bismuth based photocatalysts.

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Metadata

Authors
Zhang, L., Wang, W., Jiang, D., Gao, E., & Sun, S.
Venue
Nano Research
Published
2014-09-20
Volume
8
Issue
3
Pages
821-831
ISSN
  • 1998-0000 (ISSN-L)
  • 1998-0124
OpenAlex
W2171924066
Cited by
393
References
1
FWCI
7.42
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Photoreduction of CO2 on BiOCl nanoplates with the assistance of photoinduced oxygen vacancies. https://app.cochat.ai/papers/10.1007/s12274-014-0564-2
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Zhang, L., Wang, W., Jiang, D., Gao, E., & Sun, S. (2015). Photoreduction of CO2 on BiOCl nanoplates with the assistance of photoinduced oxygen vacancies. Nano Research. https://doi.org/10.1007/s12274-014-0564-2

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