The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Photoreduction of CO2 on BiOCl nanoplates with the assistance of photoinduced oxygen vacancies
Abstract
CO 2 photoreduction by semiconductors is of growing interest. Fabrication of oxygen-deficient surfaces is an important strategy for enhancing CO 2 photoreduction activity. However, regeneration of the oxygen vacancies in photocatalysts is still a problem since an oxygen vacancy will be filled up by the O atom from CO 2 after the dissociation process. Herein, we have fabricated highly efficient BiOCl nanoplates with photoinduced oxygen vacancies. Oxygen vacancies were easily regenerated by light irradiation due to the high oxygen atom density and low Bi-O bond energy even when the oxygen vacancies had been filled up by the O atom in the photocatalytic reactions. These oxygen vacancies not only enhanced the trapping capability for CO 2 , but also enhanced the efficiency of separation of electron-hole pairs, which resulted in the photocatalytic CO 2 reduction under simulated solar light. Furthermore, the generation and recovery of the defects in the BiOCl could be realized during the photocatalytic reduction of CO 2 in water. The existence of photoinduced defects in thin BiOCl nanoplates undoubtedly leads to new possibilities for the design of solar-driven bismuth based photocatalysts.
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Cites
Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO 2 Fixation
Appel, A. M., Bercaw, J. E., Bocarsly, A. B., Dobbek, H., DuBois, D. L., Dupuis, M., Ferry, J. G., Fujita, E., Hille, R., Kenis, P. J. A., et al. (2013) · Chemical Reviews · doi:10.1021/cr300463y · Cited by 2,193
Cited by
Ong, W.-J., Tan, L.-L., Ng, Y. H., Yong, S.-T., & Chai, S.-P. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00075 · Cited by 7,147
Recent Advances in Heterogeneous Photocatalytic CO 2 Conversion to Solar Fuels
Li, K., Peng, B., & Peng, T. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b02089 · Cited by 1,355
Gao, S., Gu, B., Jiao, X., Sun, Y., Zu, X., Yang, F., Zhu, W., Wang, C., Feng, Z., Ye, B., et al. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.6b11263 · Cited by 641
Yang, Y., Zhang, C., Lai, C., Zeng, G., Huang, D., Cheng, M., Wang, J., Chen, F., Zhou, C., & Xiong, W. (2018) · Advances in Colloid and Interface Science · doi:10.1016/j.cis.2018.03.004 · Cited by 544
Ong, W.-J., Putri, L. K., Tan, Y.-C., Tan, L.-L., Li, N., Ng, Y. H., Wen, X., & Chai, S.-P. (2017) · Nano Research · doi:10.1007/s12274-016-1391-4 · Cited by 470
Metadata
- Authors
- Zhang, L., Wang, W., Jiang, D., Gao, E., & Sun, S.
- Venue
- Nano Research
- Publisher
- Tsinghua University Press
- Published
- 2014-09-20
- Volume
- 8
- Issue
- 3
- Pages
- 821-831
- ISSN
- 1998-0000 (ISSN-L)
- 1998-0124
- OpenAlex
- W2171924066
- Cited by
- 393
- References
- 1
- FWCI
- 7.42
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhang, L., Wang, W., Jiang, D., Gao, E., & Sun, S. (2015). Photoreduction of CO2 on BiOCl nanoplates with the assistance of photoinduced oxygen vacancies. Nano Research. https://doi.org/10.1007/s12274-014-0564-2
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