The DOI matches its Crossref record; 17 of the 17 references it cites were found in a registry or an index.
Metal–organic framework derived CoSe2 nanoparticles anchored on carbon fibers as bifunctional electrocatalysts for efficient overall water splitting
Abstract
The development of efficient, low-cost, stable, non-noble-metal electrocatalysts for water splitting, particularly those that can catalyze both the hydrogen evolution reaction (HER) at the cathode and oxygen evolution reaction (OER) at the anode, is a challenge. We have developed a facile method for synthesizing CoSe 2 nanoparticles uniformly anchored on carbon fiber paper (CoSe 2 /CF) via pyrolysis and selenization of in situ grown zeolitic imidazolate framework-67 (ZIF-67). CoSe 2 /CF shows high and stable catalytic activity in both the HER and OER in alkaline solution. At a low cell potential, i.e., 1.63 V, a water electrolyzer equipped with two CoSe 2 /CF electrodes gave a water-splitting current of 10 mA·cm −2 . At a current of 20 mA·cm −2 , it can operate without degradation for 30 h. This study not only offers a cost-effective solution for water splitting but also provides a new strategy for developing various catalytic nanostructures by changing the metal–organic framework precursors.
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Cites
Metal-organic framework materials as catalysts
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Cited by
Non‐Noble Metal‐based Carbon Composites in Hydrogen Evolution Reaction: Fundamentals to Applications
Wang, J., Xu, F., Jin, H., Chen, Y., & Wang, Y. (2017) · Advanced Materials · doi:10.1002/adma.201605838 · Cited by 1,769
Cheng, N., Ren, L., Xu, X., Du, Y., & Dou, S. X. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201801257 · Cited by 359
Recent progress in transition metal selenide electrocatalysts for water splitting
Xia, X., Wang, L., Sui, N., Colvin, V. L., & Yu, W. W. (2020) · Nanoscale · doi:10.1039/d0nr02939d · Cited by 336
Liu, X., Zhou, Y., Zhang, J., Tang, L., Luo, L., & Zeng, G. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b02563 · Cited by 312
MOF-derived nanohybrids for electrocatalysis and energy storage: current status and perspectives
Zhang, H., Liu, X., Wu, Y., Guan, C., Cheetham, A. K., & Wang, J. (2018) · Chemical Communications · doi:10.1039/c8cc00789f · Cited by 309
Metadata
- Authors
- Sun, C., Dong, Q., Yang, J., Dai, Z., Lin, J., Chen, P., Huang, W., & Dong, X.
- Venue
- Nano Research
- Publisher
- Tsinghua University Press
- Published
- 2016-07-30
- Volume
- 9
- Issue
- 8
- Pages
- 2234-2243
- ISSN
- 1998-0000 (ISSN-L)
- 1998-0124
- OpenAlex
- W2488081766
- Cited by
- 231
- References
- 17
- FWCI
- 9.92
- Type
- journal article
- Language
- en
- Open access
- closed
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- Sun, C., Dong, Q., Yang, J., Dai, Z., Lin, J., Chen, P., Huang, W., & Dong, X. (2016). Metal–organic framework derived CoSe2 nanoparticles anchored on carbon fibers as bifunctional electrocatalysts for efficient overall water splitting. Nano Research. https://doi.org/10.1007/s12274-016-1110-1
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