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Embedding CoS2 nanoparticles in N-doped carbon nanotube hollow frameworks for enhanced lithium storage properties

Zhang, Jintao, Yu, Le, Lou, Xiong Wen David·2017·Nano Research

Abstract

The construction of metal sulfides-carbon nanocomposites with a hollow structure is highly attractive for various energy storage and conversion technologies. Herein, we report a facile two-step method for preparing a nanocomposite with CoS 2 nanoparticles in N-doped carbon nanotube hollow frameworks (NCNTFs). Starting from zeolitic imidazolate framework-67 (ZIF-67) particles, in situ reduced metallic cobalt nanocrystals expedite the formation of the hierarchical hollow frameworks from staggered carbon nanotubes via a carbonization process. After a follow-up sulfidation reaction with sulfur powder, the embedded cobalt crystals are transformed into CoS 2 nanoparticles. Benefitting from the robust hollow frameworks made of N-doped carbon nanotubes and highly active CoS 2 ultrafine nanoparticles, this advanced nanocomposite shows greatly enhanced lithium storage properties when evaluated as an electrode for lithium-ion batteries. Impressively, the resultant CoS 2 /NCNTF material delivers a high specific capacity of ∼937 mAh·g –1 at a current density of 1.0 A·g –1 with a cycle life longer than 160 cycles.

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Metadata

Authors
Zhang, J., Yu, L., & Lou, X. W. D.
Venue
Nano Research
Published
2017-01-10
Volume
10
Issue
12
Pages
4298-4304
ISSN
  • 1998-0000 (ISSN-L)
  • 1998-0124
OpenAlex
W2568906120
Cited by
171
References
3
FWCI
11.75
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Embedding CoS2 nanoparticles in N-doped carbon nanotube hollow frameworks for enhanced lithium storage properties. https://app.cochat.ai/papers/10.1007/s12274-016-1394-1
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Zhang, J., Yu, L., & Lou, X. W. D. (2017). Embedding CoS2 nanoparticles in N-doped carbon nanotube hollow frameworks for enhanced lithium storage properties. Nano Research. https://doi.org/10.1007/s12274-016-1394-1

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