The DOI matches its Crossref record; 6 of the 6 references it cites were found in a registry or an index.
Transition metal–nitrogen–carbon nanostructured catalysts for the oxygen reduction reaction: From mechanistic insights to structural optimization
Abstract
Accelerating the rate-limiting oxygen reduction reaction (ORR) at the cathode remains the foremost issue for the commercialization of fuel cells. Transition metal–nitrogen–carbon (M–N/C, M = Fe, Co, etc.) nanostructures are the most promising class of non-precious metal catalysts (NPMCs) with satisfactory activities and stabilities in practical fuel cell applications. However, the long-debated nature of the active sites and the elusive structure-performance correlation impede further developments of M–N/C materials. In this review, we present recent endeavors to elucidate the actual structures of active sites by adopting a variety of physicochemical techniques that may provide a profound mechanistic understanding of M–N/C catalysts. Then, we focus on the spectacular progress in structural optimization strategies for M–N/C materials with tailored precursor architectures and modified synthetic routes for controlling the structural uniformity and maximizing the number of active sites in catalytic materials. The recognition of the right active centers and site-specific engineering of the nanostructures provides future directions for designing advantageous M–N/C catalysts.
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Citations
Cites
Electrocatalyst approaches and challenges for automotive fuel cells
Debe, M. K. (2012) · Nature · doi:10.1038/nature11115 · Cited by 5,885
High-Performance Electrocatalysts for Oxygen Reduction Derived from Polyaniline, Iron, and Cobalt
Wu, G., More, K. L., Johnston, C. M., & Zelenay, P. (2011) · Science · doi:10.1126/science.1200832 · Cited by 3,984
Recent advancements in Pt and Pt-free catalysts for oxygen reduction reaction
Nie, Y., Li, L., & Wei, Z. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00484a · Cited by 2,156
Zhong, H., Wang, J., Zhang, Y., Xu, W., Xing, W., Xu, D., Zhang, Y., & Zhang, X. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201408990 · Cited by 938
Liang, H.-W., Wu, Z.-Y., Chen, L.-F., Li, C., & Yu, S.-H. (2015) · Nano Energy · doi:10.1016/j.nanoen.2014.11.008 · Cited by 440
He, W., Jiang, C., Wang, J., & Lu, L. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201404333 · Cited by 386
Self-citation
Cited by
Single-Atom Catalysts: Synthetic Strategies and Electrochemical Applications
Chen, Y., Ji, S., Chen, C., Peng, Q., Wang, D., & Li, Y. (2018) · Joule · doi:10.1016/j.joule.2018.06.019 · Cited by 2,258
Zhang, J., Zhao, Y., Chen, C., Huang, Y.-C., Dong, C.-L., Chen, C.-J., Liu, R.-S., Wang, C., Yan, K., Li, Y., et al. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b09352 · Cited by 989
Defect engineering in earth-abundant electrocatalysts for CO2 and N2 reduction
Wang, Q., Lei, Y., Wang, D., & Li, Y. (2019) · Energy & Environmental Science · doi:10.1039/c8ee03781g · Cited by 574
Porphyrin-based frameworks for oxygen electrocatalysis and catalytic reduction of carbon dioxide
Liang, Z., Wang, H.-Y., Zheng, H., Zhang, W., & Cao, R. (2021) · Chemical Society Reviews · doi:10.1039/d0cs01482f · Cited by 506
Atomic interface effect of a single atom copper catalyst for enhanced oxygen reduction reactions
Jiang, Z., Sun, W., Shang, H., Chen, W., Sun, T., Li, H., Dong, J., Zhou, J., Li, Z., Wang, Y., et al. (2019) · Energy & Environmental Science · doi:10.1039/c9ee02974e · Cited by 380
Metadata
- Authors
- Shen, M., Wei, C., Ai, K., & Lu, L.
- Venue
- Nano Research
- Publisher
- Tsinghua University Press
- Published
- 2017-01-18
- Volume
- 10
- Issue
- 5
- Pages
- 1449-1470
- ISSN
- 1998-0000 (ISSN-L)
- 1998-0124
- OpenAlex
- W2572403440
- Cited by
- 162
- References
- 6
- FWCI
- 6.12
- Type
- journal article
- Language
- en
- Open access
- closed
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- Shen, M., Wei, C., Ai, K., & Lu, L. (2017). Transition metal–nitrogen–carbon nanostructured catalysts for the oxygen reduction reaction: From mechanistic insights to structural optimization. Nano Research. https://doi.org/10.1007/s12274-016-1400-7
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