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MoS2 as a long-life host material for potassium ion intercalation

Ren, Xiaodi, Zhao, Qiang, McCulloch, William D., Wu, Yiying·2017·Nano Research

Abstract

Electrochemical potassium ion intercalation into two-dimensional layered MoS2 was studied for the first time for potential applications in the anode in potassium-based batteries. X-ray diffraction analysis indicated that an intercalated potassium compound, hexagonal K0.4MoS2, formed during the intercalation process. Despite the size of K+, MoS2 was a long-life host for repetitive potassium ion intercalation and de-intercalation with a capacity retention of 97.5% after 200 cycles. The diffusion coefficient of the K+ ions in K x MoS2 was calculated based on the Randles–Sevcik equation. A higher K+ intercalation ratio not only encountered a much slower K+ diffusion rate in MoS2, but also induced MoS2 reduction. This study shows that metal dichalcogenides are promising potassium anode materials for emerging K-ion, K-O2, and K-S batteries.

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Metadata

Authors
Ren, X., Zhao, Q., McCulloch, W. D., & Wu, Y.
Venue
Nano Research
Published
2017-02-21
Volume
10
Issue
4
Pages
1313-1321
ISSN
  • 1998-0000 (ISSN-L)
  • 1998-0124
OpenAlex
W2590484559
Cited by
316
References
32
FWCI
17.45
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: MoS2 as a long-life host material for potassium ion intercalation. https://app.cochat.ai/papers/10.1007/s12274-016-1419-9
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Ren, X., Zhao, Q., McCulloch, W. D., & Wu, Y. (2017). MoS2 as a long-life host material for potassium ion intercalation. Nano Research. https://doi.org/10.1007/s12274-016-1419-9

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