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Tuning nitrogen species in three-dimensional porous carbon via phosphorus doping for ultra-fast potassium storage

Open access
He, Hanna, Huang, Dan, Tang, Yougen, Wang, Qi, Ji, Xiaobo, Wang, Haiyan, Guo, Zaiping·2019·Nano Energy

Abstract

Abstract Carbonaceous materials have been proved to be promising materials for energy storage. Heteroatom doping, especially N doping, could further promote their electrochemical performance, and the type of doped N configuration plays a key role in determining the reactivity of doped carbon. However, achieving a high proportion of active N (pyridinic N) in N doped carbon is still a big challenge. In this work, we successfully tuned the N species and achieved high-level pyridinic N in carbon via constructing a three-dimensional (3D) honeycomb-like structure in conjunction with phosphorus doping. The 3D porous structure with sufficient pore defects and edges provides the preconditions for the formation of pyridinic N, and the subsequent P-doping leads to more open edge sites, which further facilitate the formation of pyridinic N. This modification greatly promoted the reactivity of the carbon framework, contributing to rapid interfacial K+ adsorption reactions. The as-obtained P-doped N-rich honeycomb-like carbon thus achieved ultrahigh reversible capacity and outstanding rate capability (with capacities of 419.3 and 270.4 mA h g−1 obtained at 100 and 1000 mA g−1, respectively). This outstanding performance demonstrates that adjusting the proportion of active N in N-doped carbon offers a promising approach toward excellent N-doped carbon materials for energy storage systems.

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Metadata

Authors
He, H., Huang, D., Tang, Y., Wang, Q., Ji, X., Wang, H., & Guo, Z.
Venue
Nano Energy
Publisher
Elsevier BV
Published
2019-03
Volume
57
Pages
728-736
ISSN
2211-2855 (ISSN-L)
OpenAlex
W2907338398
Cited by
401
References
38
FWCI
19.26
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: Tuning nitrogen species in three-dimensional porous carbon via phosphorus doping for ultra-fast potassium storage. https://app.cochat.ai/papers/10.1016/j.nanoen.2019.01.009
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He, H., Huang, D., Tang, Y., Wang, Q., Ji, X., Wang, H., & Guo, Z. (2019). Tuning nitrogen species in three-dimensional porous carbon via phosphorus doping for ultra-fast potassium storage. Nano Energy. https://doi.org/10.1016/j.nanoen.2019.01.009

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