The DOI matches its Crossref record; 38 of the 38 references it cites were found in a registry or an index.
Tuning nitrogen species in three-dimensional porous carbon via phosphorus doping for ultra-fast potassium storage
Open accessAbstract
Abstract Carbonaceous materials have been proved to be promising materials for energy storage. Heteroatom doping, especially N doping, could further promote their electrochemical performance, and the type of doped N configuration plays a key role in determining the reactivity of doped carbon. However, achieving a high proportion of active N (pyridinic N) in N doped carbon is still a big challenge. In this work, we successfully tuned the N species and achieved high-level pyridinic N in carbon via constructing a three-dimensional (3D) honeycomb-like structure in conjunction with phosphorus doping. The 3D porous structure with sufficient pore defects and edges provides the preconditions for the formation of pyridinic N, and the subsequent P-doping leads to more open edge sites, which further facilitate the formation of pyridinic N. This modification greatly promoted the reactivity of the carbon framework, contributing to rapid interfacial K+ adsorption reactions. The as-obtained P-doped N-rich honeycomb-like carbon thus achieved ultrahigh reversible capacity and outstanding rate capability (with capacities of 419.3 and 270.4 mA h g−1 obtained at 100 and 1000 mA g−1, respectively). This outstanding performance demonstrates that adjusting the proportion of active N in N-doped carbon offers a promising approach toward excellent N-doped carbon materials for energy storage systems.
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Li, Y., Xiao, K., Huang, C., Wang, J., Gao, M., Hu, A., Tang, Q., Fan, B., Xu, Y., & Chen, X. (2021) · Nano-Micro Letters · doi:10.1007/s40820-020-00525-y · Cited by 892
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Metadata
- Authors
- He, H., Huang, D., Tang, Y., Wang, Q., Ji, X., Wang, H., & Guo, Z.
- Venue
- Nano Energy
- Publisher
- Elsevier BV
- Published
- 2019-03
- Volume
- 57
- Pages
- 728-736
- ISSN
- 2211-2855 (ISSN-L)
- OpenAlex
- W2907338398
- Cited by
- 401
- References
- 38
- FWCI
- 19.26
- Type
- journal article
- Language
- en
- Open access
- green
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