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Isotope geochemistry of sedimentary sulfates
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“The d34Ssulfate variations in 'Phanerozoic' oceans, based on evaporites (Claypool et al., 1980; Holser and Kaplan, 1966), form an overall trough-like trend similar to strontium isotopes (Figure 30).”
From Evolution of Sedimentary Rocks (2014) · cites this paper as Holser and Kaplan, 1966
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“The successive phases of precipitation from a limited aqueous sulphate reservoir deplete the remaining sulphate reservoir in heavy isotopes (Holser & Kaplan, 1966; Pierre, 1989).”
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“111.4‰, Fig. 9) that agrees with the values usually accepted for marine Tertiary sulphates ( Holser and Kaplan, 1966; Claypool et al., 1980).”
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“This pattern was originally noted in the evaporite record by Ault and Kulp 87 (1959) and reaffirmed by more extensive evaporite compilations (Claypool et al., 1980; 88 Holser et al., 1989; Holser & Kaplan, 1966; Strauss, 1997).”
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“The mean d34S of the Castile sulfate samples (111.6‰) coincides with the d34S of sulfate in seawater of Permian time (19.5 to 112.5‰) (see data of Holser and Kaplan 1966 and Claypool et al. 1980).”
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“Therefore, when sulfate-bearing fluids are not sufficiently supplied to a closed or partially closed basin, the remaining aqueous sulfate after progressive evaporation and gypsum precipitation would be depleted in S and O resulting in lower δS and δO values in the gypsum subsequently crystallized (Holser and Kaplan, 1…”
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“In contrast, oxidation of sulphides and dissolution of sulphate minerals typically results in only minor sulphur isotope selectivity (e.g. Holser and Kaplan, 1966; Chambers and Trudinger, 1979).”
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“the neutralized sulfuric acid solution would be expected to exhibit negligible isotope fractionation for dS (e.g., Thode and Monster, 1965; Holser and Kaplan, 1966; Raab and Spiro, 1991) and minor fractionation for dO (Lloyd, 1968).”
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“, 2018); gray circles5 evaporites data (Holser and Kaplan, 1966; Sakai, 1972; Claypool et al., 1980; Cortecci et al., 1981; Pierre and Rouchy, 1986; Das et al., 1990; Rick, 1990; Utrilla et al., 1992; Fox and Videtich, 1997; Strauss, 1997; Worden et al., 1997; Kampschulte et al., 1998; Strauss, 1993; Strauss et al., 2…”
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Metadata
- Authors
- Holser, W. T., & Kaplan, I. R.
- Affiliations
- University of California System (US)
- Venue
- Chemical Geology
- Publisher
- Elsevier BV
- Published
- 1966
- Volume
- 1
- Pages
- 93-135
- ISSN
- 0009-2541 (ISSN-L)
- OpenAlex
- W2019135021
- Cited by
- 550
- References
- 0
- Citations by year
- 2026: 10 · 2025: 11 · 2024: 7 · 2023: 7 · 2022: 16 · 2021: 13 · 2020: 15 · 2019: 12 · 2018: 11 · 2017: 10 · 2016: 9 · 2015: 5 · 2014: 9 · 2013: 10 · 2012: 10
- FWCI
- 12.91
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Chemical Geology (publishedVersion)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Paleontology › Paleontology and Stratigraphy of Fossils
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Elemental Analysis
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geological and Geochemical Analysis
- Keywords
- anhydrite, gypsum, sulfur isotopes, δ34S, paleoceanography, sulfur cycling, Late Paleozoic, Mesozoic, Tertiary, Late Permian, evaporites, paleogeography, tectonic change
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