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Isotope geochemistry of sedimentary sulfates
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“The d34Ssulfate variations in 'Phanerozoic' oceans, based on evaporites (Claypool et al., 1980; Holser and Kaplan, 1966), form an overall trough-like trend similar to strontium isotopes (Figure 30).”
From Evolution of Sedimentary Rocks (2014) · cites this paper as Holser and Kaplan, 1966
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Chapter 6.1 The Biological Sulfur Cycle
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“For example, dissolved sulfate in isolated bottom water of a stratified water column will become progressively enriched in 34S because 32S is preferentially reduced in the water column by bacteria and removed to the sediment as pyrite (Holser and Kaplan, 1966).”
BackgroundSong, W., Wu, P., Liu, J.-Z., Li, J., Wang, Z.-P., Tan, Q.-P., & Xie, Z.-J. (2022) · Ore Geology Reviews · doi:10.1016/j.oregeorev.2022.104782 · Cited by 16
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“…value of 21 % with an analytical precision of ±0.2 % (Rees 1970; Paytan et al. 1998). d34O isotopic values of both formations are similar to current marine waters, and they mark marine origin (Holser and Kaplan 1966; Claypool et al. 1980; Utrilla et al. 1992; Kasprzyk 2003; Palmer et al. 2004).”
BackgroundInfluentialIsotopes as tracers in a contaminated fractured chalk aquitard.
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24 The Assessment of the Viability of Halophilic Microorganisms in Natural Communities
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“Negative 634S values typically indicate that the source of sulfur is weathered sulfide from shales, whereas positive values generally indicate an evaporitic mineral source (Holser and Kaplan, 1966; Hitchon and Krouse, 1972; Hoefs, 1980).”
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“…of sulphur in ore-forming fluids, and each source has a distinct δ34S value: (1) mantle or magmatic sulphur (0 ± 3‰; Chaussidon and Lorand 1990), (2) marine/seawater sulphur (~ 20‰; Holser and Kaplan 1966; Claypool et al. 1980), and (3) reduced sulphur in sedimentary rocks (< 0‰; Rollinson 1993).”
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“, 2010, 2014); gray circles, evaporites data (Bernasconi et al., 2017; Claypool et al., 1980; Cortecci et al., 1981; Crockford et al., 2019; Das et al., 1990; Fox and Videtich, 1997; Holser and Kaplan, 1966; Kampschulte et al., 1998; Longinelli and Flora, 2007; Orti et al., 2010; Peryt et al., 2005; Pierre and Rouchy,…”
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“Therefore, sulfur fractionation between sulfate minerals and aqueous sulfates is small, as was underlined by several authors (Ault & Kulp, 1959; Holser & Kaplan, 1966; Sakai, 1968; Raab & Spiro, 1991).”
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Sulfur in the Earth's Crust, its Origin and Natural Cycle
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Microsensor for total dissolved sulfide (TDS).
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Isotope composition (δ34S, δ18O) of the Middle Triassic-Early Jurassic sulfates in eastern Iberia
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“1980; Holser and Kaplan 1966; Kaufman and Knoll 1995; Kaufman et al.”
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“…of the sulfur isotope composition of marine sulfates, which provides insight not only into the conditions of postdepositional transformations (as considered above) but also into the content of atmospheric oxygen and sulfate in the World Ocean, were taken 50 years ago (Holser and Kaplan, 1966).”
BackgroundSulfur Isotopes in Plutonic Rocks of the Great Basin as Indicators of Crustal Architecture
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A Geochemical and Isotopic Approach to Delineate Landfill Leachates in an RCRA Study
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Isotopic composition of dissolved sulphate and hydrogen sulphide from some thermal springs of Sicily
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The ljubija geothermal field: A herald of the pangea break-up (NW Bosnia and Herzegovina)
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“Specifically, due to limited isotopic fractionation (0‰–2‰) during sulfate mineral crystallization and dissolution (Holser & Kaplan, 1966; Thode & Monster, 1965), the isotopic composition of sedimentary marine evaporites is widely used as a faithful proxy for the reconstruction of paleo-seawater…”
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“In nature, secondary polyhalite is usually formed in the early stage of diagenesis by metasomatism of K–Mg–SO4-type brine with gypsum, anhydrite or glauberite being formed (e.g., Braitsch 1962; Holser 1966; Busson and perthuisot 1977; Pierre 1985; Warren, 2006).”
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“…× (1 − 𝑓𝑓𝑝𝑝𝑝𝑝𝑝𝑝) = 𝛿𝛿34𝑆𝑆𝑟𝑟𝑟𝑟𝑟𝑟 − 𝛿𝛿34𝑆𝑆𝑒𝑒𝑟𝑟 𝛿𝛿34𝑆𝑆𝑝𝑝𝑝𝑝 − 𝛿𝛿34𝑆𝑆𝑒𝑒𝑟𝑟 − 𝜀𝜀𝑝𝑝𝑝𝑝𝑝𝑝 × 𝑓𝑓𝑝𝑝𝑝𝑝𝑝𝑝 𝛿𝛿34𝑆𝑆𝑝𝑝𝑝𝑝 − 𝛿𝛿34𝑆𝑆𝑒𝑒𝑟𝑟 , (4) Taking the mean δ 34S values of riverine sulfate, evaporite, and pyrite as 4.8, 17, and…”
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Metadata
- Authors
- Holser, W. T., & Kaplan, I. R.
- Affiliations
- University of California System (US)
- Venue
- Chemical Geology
- Publisher
- Elsevier BV
- Published
- 1966
- Volume
- 1
- Pages
- 93-135
- ISSN
- 0009-2541 (ISSN-L)
- OpenAlex
- W2019135021
- Cited by
- 550
- References
- 0
- Citations by year
- 2026: 10 · 2025: 11 · 2024: 7 · 2023: 7 · 2022: 16 · 2021: 13 · 2020: 15 · 2019: 12 · 2018: 11 · 2017: 10 · 2016: 9 · 2015: 5 · 2014: 9 · 2013: 10 · 2012: 10
- FWCI
- 12.91
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Chemical Geology (publishedVersion)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Paleontology › Paleontology and Stratigraphy of Fossils
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Elemental Analysis
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geological and Geochemical Analysis
- Keywords
- anhydrite, gypsum, sulfur isotopes, δ34S, paleoceanography, sulfur cycling, Late Paleozoic, Mesozoic, Tertiary, Late Permian, evaporites, paleogeography, tectonic change
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