Corrosion of austenitic steels in molten sulphate deposits
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The maximum corrosion rate of the three austenitic steels at ~680°C is tentatively ascribed to decomposition of Fe2(SO4)3 to Fe2O3 near 700°C, which hinders diffusion of SO3 through the molten salt to the oxide/salt interface.
“This observation is tentatively ascribed to the decomposition of Fe2(SO4)3 to Fe2O3 at a temperature near 700 o C, hindering the diffusion of SO3 through the molten salt to the oxide/salt interface [89].”
From A review on molten sulfate salts induced hot corrosion (2021) · cites this paper as [89]
Three austenitic steels (AISI 316, AISI 347 and Esshete 1250) in a simulated coal fired boiler environment have a maximum corrosion rate at ~680°C in the temperature range 600-750°C.
“in a temperature range of 600 o C -750 o C and found that all these three stainless steels have a maximum corrosion rate at ~680 o C.”
From A review on molten sulfate salts induced hot corrosion (2021) · cites this paper as [89]
Cites
Mechanisms for the hot corrosion of nickel-base alloys
Goebel, J. A., Pettit, F. S., & Goward, G. W. (1973) · Metallurgical Transactions · doi:10.1007/bf02649626 · Cited by 420 · see citing works
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A review on molten sulfate salts induced hot corrosion
Hu, S., Finklea, H., & Liu, X. (2021) · Journal of Materials Science & Technology · doi:10.1016/j.jmst.2021.03.013 · Cited by 183 · see citing works
Shi, L., Zhang, Y., & Shih, S. (1992) · Oxidation of Metals · doi:10.1007/bf00665661 · Cited by 13 · see citing works
- Authors
- Hendry, A., & Lees, D. J.
- Affiliations
- Newcastle University (GB)
- Venue
- Corrosion Science
- Publisher
- Elsevier BV
- Published
- 1980-01
- Volume
- 20
- Issue
- 3
- Pages
- 383-404
- ISSN
- 0010-938X (ISSN-L)
- OpenAlex
- W2092034387
- Cited by
- 41
- References
- 1
- Citations by year
- 2025: 2 · 2024: 2 · 2023: 2 · 2022: 2 · 2021: 2 · 2019: 1 · 2018: 2 · 2017: 1 · 2016: 2 · 2015: 1 · 2014: 1 · 2013: 2 · 2012: 1
- FWCI
- 5.75
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Corrosion Science (publishedVersion)
- Topics
- Physical Sciences › Engineering › Aerospace Engineering › High-Temperature Coating Behaviors
- Physical Sciences › Materials Science › Materials Chemistry › Corrosion Behavior and Inhibition
- Physical Sciences › Engineering › Mechanical Engineering › High Temperature Alloys and Creep
- Keywords
- fireside corrosion, austenitic stainless steel, superheater tubes, coal-fired boilers, melting behavior, heat flux, corrosion rate prediction
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