Mechanisms for the hot corrosion of nickel-base alloys
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In an oxidizing atmosphere, the protective oxide layer is mainly composed of chromium oxides and iron oxide for iron-based alloys, and chromium oxides, cobalt oxide and nickel oxide for nickel-based alloys.
“In an oxidizing atmosphere, the protective oxide layer is mainly composed of chromium oxides and iron oxide for iron-based alloys [78] and chromium oxides, cobalt oxide and nickel oxide for nickel-based alloys [22, 32].”
From A review on molten sulfate salts induced hot corrosion (2021) · cites this paper as [22]
The initial stage of hot corrosion of Ni is independent of the amount of Na2SO4 covering the surface (0.5, 2.7 and 11.3 mg cm-2).
“Goebel et al. observed that the initial stage of hot corrosion of Ni is independent of the amount of Na2SO4 covered the surface (0.5, 2.7 and 11.3 mg cm -2 , respectively) [22].”
From A review on molten sulfate salts induced hot corrosion (2021) · cites this paper as [22]
The addition of V2O5 in Na2SO4 melt can promote the decomposition of Al2O3 and Cr2O3.
“Goebel et al. proved that the addition of V2O5 in Na2SO4 melt can even promote the decomposition of Al2O3 and Cr2O3 [22].”
From A review on molten sulfate salts induced hot corrosion (2021) · cites this paper as [22]
The addition of some acid metal oxides, i.e., V2O5, WO3 and MoO3, results in catastrophic corrosion.
“Furthermore, the addition of some acid metal oxides, i.e., V2O5, WO3 and MoO3, results in catastrophic corrosion [20, 22], as discussed below.”
From A review on molten sulfate salts induced hot corrosion (2021) · cites this paper as [22]
A faster corrosion rate in the propagation stage of Ni under more Na2SO4 is observed.
“Moreover, a faster corrosion rate in the propagation stage of Ni under more Na2SO4 is observed [22].”
From A review on molten sulfate salts induced hot corrosion (2021) · cites this paper as [22]
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Natesan, K. (1993) · Surface and Coatings Technology · doi:10.1016/0257-8972(93)90251-i · Cited by 31 · see citing works
Rapp, R. A. (1989) · Studies in inorganic chemistry · doi:10.1016/b978-0-444-88534-0.50016-3 · Cited by 31 · see citing works
Hot Corrosion of Shipboard Gas Turbine Blades
Meisner, K. J., & Opila, E. J. (2020) · Oxidation of Metals · doi:10.1007/s11085-020-09990-7 · Cited by 30 · see citing works
Kannan, A. R., Rajkumar, V., Prasad, C. D., Shanmugam, N. S., & Yoon, J. (2023) · Vacuum · doi:10.1016/j.vacuum.2023.111901 · Cited by 30 · see citing works
High-Temperature Corrosion Resistance
Birks, N., Meier, G. H., & Pettit, F. S. (1987) · JOM · doi:10.1007/bf03257568 · Cited by 30 · see citing works
Self-citation
- Authors
- Goebel, J. A., Pettit, F. S., & Goward, G. W.
- Affiliations
- Pratt & Whitney (United States) (US)
- Venue
- Metallurgical Transactions
- Published
- 1973-01
- Volume
- 4
- Issue
- 1
- Pages
- 261-278
- ISSN
- 0026-086X (ISSN-L)
- 2379-0083
- OpenAlex
- W2058048767
- Cited by
- 420
- References
- 14
- Citations by year
- 2026: 20 · 2025: 13 · 2024: 19 · 2023: 19 · 2022: 11 · 2021: 15 · 2020: 15 · 2019: 9 · 2018: 9 · 2017: 14 · 2016: 14 · 2015: 9 · 2014: 8 · 2013: 14 · 2012: 6
- FWCI
- 56.21
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- Locations
- Metallurgical Transactions (publishedVersion)
- Topics
- Physical Sciences › Engineering › Aerospace Engineering › High-Temperature Coating Behaviors
- Physical Sciences › Engineering › Mechanical Engineering › High Temperature Alloys and Creep
- Physical Sciences › Engineering › Mechanical Engineering › Intermetallics and Advanced Alloy Properties
- Keywords
- hot corrosion, nickel-based alloys, sodium sulfate, accelerated oxidation, catastrophic oxidation, sulfur diffusion, sulfidation, molybdenum, tungsten, vanadium, chromium, aluminum, protective oxide scale
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