Hydrogen and oxygen isotope fractionation during crystallization of mirabilite and ice
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The fractionation factor 10^3 ln α for H2O(s)-2.5 M NaCl at -10°C is 2.2.
“6 H20(s)-2.5 M NaCl. | | -10 | 2.2 | ..... | Stewart (1974).”
From Compilation of stable isotope fractionation factors of geochemical interest (1977) · cites this paper as Stewart (1974)
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Compilation of stable isotope fractionation factors of geochemical interest
Friedman, I., & O'Neil, J. R. (1977) · Professional Paper · doi:10.3133/pp440kk · Cited by 2,646 · see citing works
Chapter 3 – ENVIRONMENTAL ISOTOPES IN LAKE STUDIES
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The role of seawater freezing in the formation of subsurface brines
Herut, B., Starinsky, A., Katz, A., & Bein, A. (1990) · doi:10.1016/0016-7037(90)90190-v · Cited by 118
Deuterium Fractionation Between Aqueous Salt Solutions and Water Vapor
Stewart, M., & Friedman, I. (1975) · Journal of Geophysical Research Atmospheres · doi:10.1029/jc080i027p03812 · Cited by 86 · see citing works
Self-citationHigh arsenic groundwater in the Guide basin, northwestern China: Distribution and genesis mechanisms
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“on hydrogen and oxygen isotope fractionation as ice formation (Stewart, 1974), thus the relationship between dH and dO was not able to further constrain the potential for mirabilite precipitation.”
BackgroundIsotopic composition of gypsum hydration water in selected landforms from central Iran
Khademi, H., Mermut, A., & Krouse, H. (1997) · doi:10.1016/s0009-2541(97)00017-x · Cited by 59
Chapter 8 – OXYGEN AND HYDROGEN ISOTOPE EFFECTS IN LOW-TEMPERATURE MINERAL-WATER INTERACTIONS
Savin, S. (1980) · Elsevier eBooks · doi:10.1016/b978-0-444-41780-0.50014-6 · Cited by 54 · see citing works
Zhang, J., Létolle, R., Martin, J., Jusserand, C., & Mouchel, J. (1990) · doi:10.1016/0278-4343(90)90057-s · Cited by 48
Triple oxygen isotope systematics of structurally bonded water in gypsum
Herwartz, D., Surma, J., Voigt, C., Assonov, S., & Staubwasser, M. (2017) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2017.04.026 · Cited by 45 · see citing works
Farpoor, M., & Krouse, H. (2008) · Geoderma · doi:10.1016/j.geoderma.2008.06.002 · Cited by 43 · see citing works
“Stable isotope geochemistry is one of the most reliable techniques to study the origin of gypsum and more soluble salts in soils and sediments (Stewart, 1974; Sofer, 1978; Resacher et al., 2003).”
BackgroundFarpoor, M., Khademi, H., Eghbal, M., & Krouse, H. (2004) · Geoderma · doi:10.1016/j.geoderma.2003.11.013 · Cited by 41 · see citing works
Isotopic Evolution of Saline Lakes in the Low-Latitude and Polar Regions
Horita, J. (2009) · doi:10.1007/s10498-008-9050-3 · Cited by 38
“In contrast, a steeper slope of the fractionation (10.8) that was observed during freezing at the stage of mirabilite precipitation at -10C ( Stewart 1974 ) is due probably to the isotope salt effect on d2H values in the concentrated (2‐2.5 molal) NaCl solutions and seawater:”
BackgroundInfluentialSmith, G. I., Friedman, I., & McLaughlin, R. J. (1987) · doi:10.1016/0016-7037(87)90095-0 · Cited by 36
Oxygen isotope fractionation between analcime and water: An experimental study
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Variations of Stable Isotope Ratios in Nature
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Tomaru, H., Torres, M., Matsumoto, R., & Borowski, W. (2006) · doi:10.1029/2005gc001207 · Cited by 29
“In addition, the results of Stewart [1974] indicate that the isotopic fractionation during ice formation in hyper-saline water is not significantly different from the values obtained in a seawater medium.”
ResultTaylor, H. (1975) · doi:10.1016/0012-8252(81)90047-7 · Cited by 24
Stable isotope fractionation factors of water in hydrated saline mineral-brine systems
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Pagé, P., Michaud, J., Ouellet, M., & Dickman, M. (1987) · doi:10.1139/e87-023 · Cited by 14
Hydrogen and oxygen isotope studies on the McMurdo Ice Shelf, Antarctica
Stewart, M. (1975) · doi:10.1080/00288306.1975.10426346 · Cited by 13
Self-citationTan, H.-B., Huang, J.-Z., Zhang, W.-J., Liu, X.-Q., Zhang, Y.-F., Kong, N., & Zhang, Q. (2014) · doi:10.1080/08120099.2014.921242 · Cited by 5
“using guanidine hydrochloride to measure d(18)O (Playa et al. 2005). Both these studies concluded that the hydrogen isotope of hydration water would be depleted in (2)H, while oxygen isotope would be enriched (18)O with respect to the mother solutions. The calculated mean fractionation factors for oxygen (1.00446 and…”
InfluentialNoto, M., Kusakabe, M., & Kometani, M. (1990) · Chemical Geology Isotope Geoscience section · doi:10.1016/0168-9622(90)90030-g · Cited by 4 · see citing works
Yang, M.-Y., Frank, T., & Fielding, C. (2020) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2019.10.027 · Cited by 3 · see citing works
Origin of blocky aragonite cement in Cenozoic glaciomarine sediments, McMurdo Sound, Antarctica
Yang, M., Frank, T. D., Fielding, C. R., Smith, M. E., & Swart, P. K. (2019) · Sedimentology · doi:10.1111/sed.12690 · Cited by 3 · see citing works
“This depletion is due to preferential uptake of 18O by solid phases, such as sea ice and salt precipitates, during progressive seawater freezing (Stewart, 1974; Horita, 2008; Toyota et al., 2013).”
BackgroundAn improved mass spectrometric method for determining the hydrogen deuterium abundance ratio
Terwilliger, D. (1977) · doi:10.1016/0020-7381(77)80065-x · Cited by 3
Hydrochemistry and formation of shallow-buried brines in the Bankog Co Salt Lake, Xizang
Li, W.-J., Li, X., Li, Q.-K., Zhang, Q., Fan, Q.-S., Chen, T.-Y., Zhao, C.-T., Du, Y.-S., & Wei, Y. (2026) · Journal of Oceanology and Limnology · doi:10.1007/s00343-025-5187-9 · Cited by 1 · see citing works
Yang, M., Frank, T. D., Fielding, C. R., & Chang, B. (2024) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2024.118641 · Cited by 1 · see citing works
Origin of sulfur and mode of gypsum formation in central Iraqi soils
Aljeboory, S. R., Muhaimeed, A., Farpoor, M., & SALIeM, K. (2013) · Journal of Mountain Science · doi:10.1007/s11629-013-2727-0 · Cited by 1 · see citing works
“Stable isotope has been used as a reliable technique to study the origin of gypsum in soils and sediments throughout the world (Stewart 1974; Resacher et al. 2003).”
MethodKakiuchi, M. (2006) · Isotopes in environmental and health studies · doi:10.1080/10256010600840028 · Cited by 1 · see citing works
Garrett, D. E. (2001) · Elsevier eBooks · doi:10.1016/b978-012276151-5/50005-x · Cited by 9 · see citing works
- Authors
- Stewart, M. K.
- Affiliations
- University of Pennsylvania (US)
- Corresponding author
- Stewart, Michael K.
- ORCID
- Stewart, Michael K.
- Venue
- Geochimica et Cosmochimica Acta
- Publisher
- Elsevier BV
- Published
- 1974-01
- Volume
- 38
- Issue
- 1
- Pages
- 167-172
- ISSN
- 0016-7037 (ISSN-L)
- OpenAlex
- W1976610216
- Cited by
- 39
- References
- 0
- Citations by year
- 2026: 1 · 2024: 1 · 2022: 1 · 2021: 1 · 2019: 2 · 2018: 2 · 2017: 1 · 2015: 1 · 2014: 1 · 2013: 2
- FWCI
- 7.11
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Geochimica et Cosmochimica Acta (publishedVersion)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Groundwater and Isotope Geochemistry
- Physical Sciences › Earth and Planetary Sciences › Geophysics › Geological and Geochemical Analysis
- Physical Sciences › Earth and Planetary Sciences › Atmospheric Science › Geology and Paleoclimatology Research
- Keywords
- hydrogen isotope fractionation, oxygen isotope fractionation, mirabilite, ice, crystallization, deuterium, oxygen-18, NaCl solution, seawater, equilibrium fractionation factors
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